电气化学的免职制作的一个高度敏感的安培计的磺胺嘧啶传感器 poly (钴 tetraaminophthalocyanine )(poly (CoIITAPc )) 在多围的碳 nanotubes-Nafion (MWCNTs-Nafion ) 的表面上,修改电极被描述。这个电极由联合 CoIITAPc, MWCNT,和 Nafion 的优点显示出很吸引人的表演。与赤裸的玻璃质的碳相比,电极(GCE ) 和 MWCNTs-Nafion 修改了电极, electrocatalytic 活动(CoIITAPc ) poly,极大地产生的涂的 MWCNTs-Nafion GCE 包括低氧化潜力,高当前的回答,和好犯规反的性能向磺胺嘧啶改进了电气化学的察觉。当与 0.17 mol/L 的察觉限制从 0.5 ~ 43.5 mol/L 增加磺胺嘧啶的集中时,在新修改电极上获得的磺胺嘧啶的氧化山峰水流线性地增加了。
A highly sensitive amperometric sulfadiazine sensor fabricated by electrochemical deposition of poly(cobalt tetraaminophthalocyanine) (poly(Co II TAPc)) on the surface of a multi-walled carbon nanotubes-Nafion (MWCNTs-Nafion) modified electrode is described.This electrode showed a very attractive performance by combining the advantages of Co II TAPc,MWCNTs,and Nafion.Compared with the bare glassy carbon electrode (GCE) and the MWCNTs-Nafion modified electrode,the electrocatalytic activity of poly(Co II TAPc)-coated MWCNTs-Nafion GCE generated greatly improved electrochemical detections toward sulfadiazine including low oxidation potential,high current responses,and good anti-fouling performance.The oxidation peak currents of sulfadiazine obtained on the new modified electrode increased linearly while increasing the concentration of sulfadiazine from 0.5 to 43.5 μmol/L with the detection limit of 0.17 μmol/L.