位置:成果数据库 > 期刊 > 期刊详情页
Electrocatalytic response of poly(cobalt tetraaminophthalocyanine)/multi-walled carbon nanotubes-Nafion modified electrode toward sulfadiazine in urine
  • ISSN号:1673-1581
  • 期刊名称:《浙江大学学报:B卷英文版》
  • 时间:0
  • 分类:O69[理学—化学]
  • 作者机构:[1]Department of Chemistry, Zhejiang University, Hangzhou 310028, China, [2]Department of Chemistry, Zhejiang Sci-Tech University, Hangzhou 310018, China, [3]Department of Stomatology, the Second Affiliated Hospital, School of Medicine, Zhejiang University, Hangzhou 310009, China
  • 相关基金:Project supported by the National Natural Science Foundation of China (Nos.20803067 and 20911140271); the Qianjiang Talents Project of the Technology Office of Zhejiang Province (No.2009R10029); the Natural Science Foundation of Zhejiang Province (No.Y5110054),China
中文摘要:

电气化学的免职制作的一个高度敏感的安培计的磺胺嘧啶传感器 poly (钴 tetraaminophthalocyanine )(poly (CoIITAPc )) 在多围的碳 nanotubes-Nafion (MWCNTs-Nafion ) 的表面上,修改电极被描述。这个电极由联合 CoIITAPc, MWCNT,和 Nafion 的优点显示出很吸引人的表演。与赤裸的玻璃质的碳相比,电极(GCE ) 和 MWCNTs-Nafion 修改了电极, electrocatalytic 活动(CoIITAPc ) poly,极大地产生的涂的 MWCNTs-Nafion GCE 包括低氧化潜力,高当前的回答,和好犯规反的性能向磺胺嘧啶改进了电气化学的察觉。当与 0.17 mol/L 的察觉限制从 0.5 ~ 43.5 mol/L 增加磺胺嘧啶的集中时,在新修改电极上获得的磺胺嘧啶的氧化山峰水流线性地增加了。

英文摘要:

A highly sensitive amperometric sulfadiazine sensor fabricated by electrochemical deposition of poly(cobalt tetraaminophthalocyanine) (poly(Co II TAPc)) on the surface of a multi-walled carbon nanotubes-Nafion (MWCNTs-Nafion) modified electrode is described.This electrode showed a very attractive performance by combining the advantages of Co II TAPc,MWCNTs,and Nafion.Compared with the bare glassy carbon electrode (GCE) and the MWCNTs-Nafion modified electrode,the electrocatalytic activity of poly(Co II TAPc)-coated MWCNTs-Nafion GCE generated greatly improved electrochemical detections toward sulfadiazine including low oxidation potential,high current responses,and good anti-fouling performance.The oxidation peak currents of sulfadiazine obtained on the new modified electrode increased linearly while increasing the concentration of sulfadiazine from 0.5 to 43.5 μmol/L with the detection limit of 0.17 μmol/L.

同期刊论文项目
同项目期刊论文
期刊信息
  • 《浙江大学学报:B卷英文版》
  • 中国科技核心期刊
  • 主管单位:
  • 主办单位:浙江大学
  • 主编:
  • 地址:杭州玉古路20号,浙江大学学报《英文版》编辑部
  • 邮编:310027
  • 邮箱:jzus@zju.edu.cn
  • 电话:0571-87952276 87952331
  • 国际标准刊号:ISSN:1673-1581
  • 国内统一刊号:ISSN:33-1356/Q
  • 邮发代号:
  • 获奖情况:
  • 国内外数据库收录:
  • 被引量:323