以固体废物煤矸石为原料,采用“高温焙烧活化-碱熔融-碱溶-陈化-晶化”水热反应体系,根据Y型沸石相应的结构特征,通过对各阶段反应条件的探究及对SiO2/Al2O3的摩尔比的控制,合成Y型沸石,其结构、形貌和性能经X-射线荧光光谱、X-射线衍射、扫描电子显微镜、Fourier红外光谱和氮吸附仪分析表征。并将Y型沸石应用于氨氮废水的处理,对其吸附性能进行研究。结果表明,在活化温度800℃,碱熔融温度850℃,碱熔融质量比(Na2CO,/煤矸石)为1.0,碱溶NaOH溶液浓度为3mol·L^-1,于60℃陈化12h,晶化温度105oC,晶化时间6h条件下,硅铝比为6—8,制得的Y型沸石结晶度最高(93%),对氨氮废水的去除率在40min内达到88.2%。
Zeolite Y was synthesized by "activated by high temperature-alkali fusion-alkali dissolution- aging-crystallize " hydrothermal system from coal gangue via the condition of each stage and the control of SiO2/Al2O3. The as-fabricated samples were characterized by X-ray fluorescence spectrum( XRF), X-ray diffraction ( XRD), scanning electron microscopy (SEM) , Fourier transform infrared spectrosco- py(FHR) and N2 adsorption-desorption. Zeolite Y was applied to the adsorption of ammonia nitrogen wastewater. The results showed that under the activation temperature of 800 ℃ and the Alkali fusion temperature of 850 ℃, mass ratio of NaECO3 and coal gangue was 1.0, concentration of NaOH was 3 mol · L^-1 , aging 12 h at 60 ℃, crystallization at 105 ℃ for 6 h, SiO2/A1203 ratio for 6 - 8, genera- ted the highest zeolite Y crystallinity (93 % ). The removal rate of ammonia nitrogen wastewater was 88.2% in 40 minutes.