利用氰尿酸为催化剂,在温和的条件下合成出了具有烷氧基的酞菁化合物。采用红外光谱(FTIR)、核磁共振谱(^1H NMR和^(13)C NMR)、X射线衍射(XRD)、差示扫描量热法(DSC)和热重分析法(TGA)多种测试手段进行了表征。表征结果证实了在不添加催化剂下,目标化合物符合预期的分子结构。通过对其反应机理研究得到此反应不需要特殊的条件,只需在少量氰尿酸存在和适当的温度下反应即可进行。
The phthalocyanine compound with alkoxy was synthesized using cyanuric acid under a mild reaction condition.The samples were characterized by infrared spectroscopy(FTIR),nuclear magnetic resonance spectrum(1H NMR and 13C NMR),X-ray diffraction(XRD),differential scanning calorimetry(DSC) and thermogravimetric analysis(TGA).The results show that without other catalyst,the molecular structures of the samples are consistent with our expectations.In addition,the reaction mechanism has been investigated and the results show that the reaction can occur under appropriate temperature with the presence of a small amount of cyanuric acid.