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改性甲基丙烯酸共聚物分散剂对陶瓷复合料浆流变性及坯体强度的影响
  • ISSN号:1000-3851
  • 期刊名称:《复合材料学报》
  • 时间:0
  • 分类:TB332[一般工业技术—材料科学与工程]
  • 作者机构:[1]陕西科技大学轻化工材料与设计研究所,咸阳712080, [2]陕西科技大学材料与工程学院,咸阳712080
  • 相关基金:国家自然科学基金资助项目(50473049)
中文摘要:

烯丙基聚氧乙烯醚与甲基丙烯酸和甲基丙烯酸甲酯可通过自由基共聚获得两亲结构的水溶性高分子MPMA,可作为陶瓷浆料分散剂。研究了MPMA用量对石英/长石/粘土复合浆料流变性及坯体强度的影响,并分析了其原因及分散稳定作用机理。结果表明:MPMA的加入显著优化了料浆的流变性能并提高了成型后陶瓷的强度。在pH值为9~10时,MPMA的最佳用量为0.57wt%(相对绝干浆料),料浆的Zeta电位绝对值由28.5mV升高到65.5mV,零剪切黏度由690.9mPa·s降低到81.6mPa·s,触变面积最小,陶瓷料浆基本呈Newton流动特性,显示了很好的分散性。与添加无机分散剂的陶瓷坯体相比,添加MPMA的陶瓷坯体强度由160MPa升高到268MPa。

英文摘要:

Through radical copolymerization, modified waterborne poly methacrylic acid (MPMA) with hydrophilic and hydrophobic groups was prepared by reacting ally poly (ehtenoxy ether), methacrylic acid and methyl methacry late. Using MPMA as ceramic dispersant, the effects of MPMA concentration on the theological behavior of Dia mond/Feldspar/Clay compound slurry and ceramic breaking strength were studied, and simultaneously the reasons and dispersive mechanism were analyzed. The results show that MPMA can improve the slurry's rheological properties and the ceramic strength. The optimum MPMA concentration is 0.57 wt% (based on the absolute dry slurry) with pH ranging from 9 to 10. When adding 0.57 wt% MPMA, the slurry's negative Zeta potential increases from 28.5 mV to 65.5 mV, and its zero shear viscosity decreases from 690.9 mPa.s to 81.6 mPa.s. At the same time, its thixotropy area reaches the minimum, and the slurry exhibits Newton flow behavior. Compared with ceramic with inorganic dispersant addition, the ceramic with MPMA addition owns higher breaking strength, which is increased from 160 MPa to 268 MPa.

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期刊信息
  • 《复合材料学报》
  • 中国科技核心期刊
  • 主管单位:工业和信息化部
  • 主办单位:北京航空航天大学 中国复合材料学会
  • 主编:益小苏
  • 地址:北京海淀区学院路37号
  • 邮编:100083
  • 邮箱:
  • 电话:010-82316907
  • 国际标准刊号:ISSN:1000-3851
  • 国内统一刊号:ISSN:11-1801/TB
  • 邮发代号:80-413
  • 获奖情况:
  • 国内外数据库收录:
  • 被引量:17731