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Bipolar charge transport property of N,N'-dicarbazolyl- 1,4-dimethene-benzene: A study of the short range order model
  • ISSN号:1005-281X
  • 期刊名称:《化学进展》
  • 时间:0
  • 分类:O212[理学—概率论与数理统计;理学—数学] TN929.11[电子电信—通信与信息系统;电子电信—信息与通信工程]
  • 作者机构:[1]Key Labaratory of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China
  • 相关基金:This work was supported by the National Basic Research and Development Program of China (2009CB623604) and the National Natural Science Foundation of China (50990060, 51073809 and 61177023). We thank Prof Shuai ZhiGang for the aid in our calculation.
中文摘要:

短范围顺序模型通常被用来解释混乱器官的半导体的充电运输性质。然而,它的有效性还没被学习。在这篇论文,洞和双极的材料的电子活动性, N, N-dicarbazolyl-1,4-dimethene-benzene (DCB ) ,整个飞行的时间被测量方法。DCB 的洞和电子活动性基于水晶的结构是计算的。为了调查短范围顺序模型,,在到电子的洞的零个电场的费用活动性的比率被计算。结果证明这个模型不能充分解释我们的案例。原因详细被讨论,并且一个修正方法被建议。没有前提,我们用短范围顺序模型显示了那解释非结晶的材料的费用运输性质可以导致偏差,它经常在过去被忽视。

英文摘要:

Short range order model is commonly used to explain the charge transport property of disordered organic semiconductors. How- ever, its validity is not yet studied. In this paper, the hole and electron mobilities of a bipolar material, N,N'-dicarbazolyl-1,4- dimethene-benzene (DCB), were measured through time of flight method. The hole and electron mobilities of DCB based on the crystalline structure were calculated. In order to investigate the short range order model, the ratios of charge mobilities at zero electric field of holes to electrons were calculated. The results showed that this model cannot fully explain our case. The reason was discussed in detail, and a correction method was proposed. We showed that using the short range order model without precondi- tions to explain the charge transport property of amorphous materials may lead to deviations, which is often neglected in the past.

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期刊信息
  • 《化学进展》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学院
  • 主办单位:中国科学院基础研究局 化学部 文献情报中心
  • 主编:
  • 地址:北京中关村四环西路33号
  • 邮编:100080
  • 邮箱:scinfo@mail.las.ac.cn
  • 电话:010-82627757
  • 国际标准刊号:ISSN:1005-281X
  • 国内统一刊号:ISSN:11-3383/O6
  • 邮发代号:82-645
  • 获奖情况:
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:21655