中文摘要：

采用离子自组装的方法，制备了侧链含有肉桂酸光敏基元和二苯乙烯荧光基元的新型超分子复合物PCAMSTIL。通过核磁共振（NMR）和红外光谱（FT-IR）表征了该超分子复合物的结构，并用热重分析（TGA）、紫外可见光谱（UV-Vis）和荧光光谱（FL）研究了其热稳定性和光学性能。将PCAMSTII。旋涂成膜，薄膜经过266nm偏振脉冲激光辐照后，肉桂酸发生轴向选择的[2＋2]加成，薄膜垂直于激光偏振方向的紫外可见吸收明显大于平行方向的吸收，证实薄膜具有取向性。取向薄膜的最大吸收二向色性取向值最大可达0．103，优于一般肉桂酸材料的取向性，肉桂酸分子的取向也引起二苯乙烯荧光分子的协同取向，荧光偏振发射比可达1．73。

英文摘要：

Supermolecular complex PCAMSTIL containing photosensitive unit （cinnamate） and fluores cent unit （stilbene） was prepared by ionic self-assembly （ISA） method. The structure of the complex was characterized by nuclear magnetic resonance （NMR） and Fourier transform infrared spectroscopy （FT- IR）. The thermal stability and optical property of the complex was studied by thermogravimetric analysis （TGA）, ultraviolet visible spectroscopy（UV-Vis） and fluorescence spectium（FL）. Irradiated by 266 nm polarized laser caused cinnamate group to undergo axis-seletive [2＋2] photocycloaddition, resulting in an alignment of cinnamate group perpendicular to the polarization direction leading to dichroism value of 0. 103. The laser-induced orientation of cinnamate group had a cooperative effect on alignment of the stil- bene-based fluorescent unit. So the fluorescence emitted by the oriented film was polarized and the ratio of anisotropic fluorescence was 1.73.