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Effect of reactive surface area of minerals on mineralization trapping of CO2 in saline aquifers
  • ISSN号:1672-5107
  • 期刊名称:Petroleum Science
  • 时间:0
  • 页码:400-407
  • 分类:O643.36[理学—物理化学;理学—化学] X703.1[环境科学与工程—环境工程]
  • 作者机构:[1]Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Beijing Key Laboratory of CO2Utilization and Reduction Technology, Department of Thermal Engineering, Tsinghua University, Beijing 100084, China
  • 相关基金:This project was supported by the National Natural Science Foundation of China (Grant No. 50906043) and the Tsinghua University Initiative Scientific Research Program (2009THZ02232). The first author did this study while at Geoscience Australia sponsored by CAGS (China-Australia Geological Storage of CO2 Project).
  • 相关项目:含盐水微细多孔结构对超临界CO2的物理捕获和溶解捕获过程的机理研究
中文摘要:

反应表面区域,控制矿物质反应的一个重要参数,影响矿化作用套住影响长期的 CO2 存储的 CO2 的数量。CO2 套住的矿化作用上的反应表面区域的效果数字地在盐的含水土层为 CO2 存储被模仿。包括钙长石,方解石和 kaolinite,三种矿物质涉及矿物质反应。这份报纸从文学基于试验性的数据为在特定的表面区域和钙长石的谷物直径之间的关系建模(Brantley 和 Mellott, 2000 ) 。当钙长石和方解石的反应表面区域从 838 ~ 83.8 m2/m3 减少时,矿化作用在 500 年以后套住 CO2 的百分比从 11.8% ~ 0.65% 减少。当钙长石和方解石的反应表面区域从 838 ~ 83.8 m2/m3 减少时,溶解钙长石的数量和猛抛的 kaolinite 和方解石的数量显著地减少。方解石开始在盐水被溶解然后在在 CO2-H2O 和矿物质之间的 geochemical 反应期间猛抛。钙长石和方解石的不同反应表面区域从溶解导致不同时间到降水。盐水的 pH 与影响盐的含水土层的酸味的钙长石和方解石的减少的反应表面区域减少。在盐的含水土层的上面、更低的部分之间的煤气的浸透与钙长石和方解石的减少的反应表面区域增加。CO2+brine 答案区域与钙长石和方解石的减少的反应表面区域增加的盐水答案表演的集体密度分发。

英文摘要:

The reactive surface area, an important parameter controlling mineral reactions, affects the amount of mineralization trapping of CO2 which affects the long-term CO2 storage. The effect of the reactive surface area on the mineralization trapping of CO2 was numerically simulated for CO2 storage in saline aquifers. Three kinds of minerals, including anorthite, calcite and kaolinite, are involved in the mineral reactions. This paper models the relationship between the specific surface area and the grain diameter of anorthite based on experimental data from literature (Brantley and Mellott, 2000). When the reactive surface areas of anorthite and calcite decrease from 838 to 83.8 m^2/m^3, the percentage of mineralization trapping of CO: after 500 years decreases from 11.8% to 0.65%. The amount of dissolved anorthite and the amounts of precipitated kaolinite and calcite decrease significantly when the reactive surface areas ofanorthite and calcite decrease from 838 to 83.8 m2/m3. Calcite is initially dissolved in the brine and then precipitates during the geochemical reactions between CO2-H20 and the minerals. Different reactive surface areas of anorthite and calcite lead to different times from dissolution to precipitation. The pH of the brine decreases with decreasing reactive surface areas of anorthite and calcite which influences the acidity of the saline aquifer. The gas saturation between the upper and lower parts of the saline aquifer increases with decreasing reactive surface areas of anorthite and calcite. The mass density distribution of brine solution shows that the CO2^+brine solution region increases with decreasing reactive surface areas ofanorthite and calcite.

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期刊信息
  • 《石油科学:英文版》
  • 主管单位:
  • 主办单位:中国石油大学
  • 主编:朱秀芹
  • 地址:北京海淀区学院路20号15号楼
  • 邮编:100083
  • 邮箱:ps0092@163.com
  • 电话:010-82370092 82375872 89734040
  • 国际标准刊号:ISSN:1672-5107
  • 国内统一刊号:ISSN:11-4995/TE
  • 邮发代号:80-379
  • 获奖情况:
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国剑桥科学文摘,美国科学引文索引(扩展库),美国石油文摘
  • 被引量:150