TM^2+:Ⅱ-Ⅵ族化合物以其可调谐范围宽、激发态吸收小、吸收和发射截面大以及室温下量子效率高等优点已成为目前最具发展潜力的中红外激光材料。本文回顾了近年来TM^2+:Ⅱ-Ⅵ族中红外激光材料在国内外的发展现状,分别从TM^2+:Ⅱ-Ⅵ族材料在激光器件上的应用以及该材料的制备方法两方面进行综述。在对该材料结构和分类进行介绍的基础上,对典型TM^2+:Ⅱ-Ⅵ族中红外激光材料的激光性能进行了详细概述,系统列举了此类中红外激光单晶和多晶材料的制备方法,指出了该领域目前存在的问题,并对其发展前景及研究趋势做了展望。
Abstract TM^2+ : Ⅱ -VI compounds have become the most potential materials used for intrared laser due to me advantage of wide tunable range, small excited state absorption, high absorption and emission cross section and high quantum efficiency at room temperature. The research progress of TM^2+ - Ⅱ -Ⅵ laser materials are retrospect in this paper. Both the applications of TM^2+ : Ⅱ -Ⅵ materials in laser devices and their preparation methods are reviewed, respectively. The laser performance of typical TM^2+ : Ⅱ -VI mid-infrared materials are summarized in detail, and the preparation methods for monocrystalline and polycrystalline of these materials are listed systematically. At last, the existing problems in this field are pointed out, and the development prospects and research trends are prospected.