位置：成果数据库 > 期刊 > 期刊详情页
Pr掺杂对Ce5.2Sm0.8MoO15-δ晶界及电性能的影响
  • ISSN号：0567-7351
  • 期刊名称：《化学学报》
  • 时间：0
  • 分类：O484.42[理学—固体物理;理学—物理]
  • 作者机构：[1]长春工业大学生物工程学院,长春130012, [2]中国科学院长春应用化学研究所稀土化学与物理重点实验室,长春130022
  • 相关基金：国家自然科学基金（Nos.20331030,20671088）资助项目.
作者： 周德凤[1], 郭微[1], 朱建新[1], 郝险峰[2], 葛志敏[1], 叶俊峰[1], 孟健[2]
关键词： 固体电解质, 电导率, 晶界, 固体氧化物燃料电池, solid state electrolyte, conductivity, grain boundary, solid oxide fuel cell
中文摘要：

在Ce5.2Sm0.8-xPrxMoO15-δ体系中引入少量Pr得新氧化物Ce5.2Sm0.72Pr0.08MoO15-δ,通过X射线衍射（XRD）,拉曼光谱（Raman）,X射线光电子能谱（XPS）,场发射扫描电镜（FE-SEM）等手段对氧化物结构进行分析,交流阻抗谱测试电性能;讨论掺杂少量Pr对Ce5.2Sm0.8MoO15-δ微观结构和电性能的影响.结果表明,少量Pr^3＋的掺杂可降低晶界电阻,增加离子扩散通道,降低体系的总电导激活能和晶界电导激活能,提高氧化物的总电导率和晶界电导率;500℃时掺Pr材料的晶界电导率为6.79×10^-3S·cm^-1,比未掺Pr材料的晶界电导率（5.61×10^-5S·cm^-1）提高约2个数量级.

英文摘要：

Material formulated as Ce5.2Sm0.8-xMoO15-δ （x = 0.08） was prepared by adding small amounts of Pr dopant in oxide Ce5.2Sm0.8-xMoO15-δ. Structural and electrical properties were investigated by means of X-ray diffraction （XRD）, Raman spectroscopy, X-ray photoelectron spectroscopy （XPS）, field emission scanning electron microscopy （FE-SEM） and AC impedance spectroscopy. The effect of small amounts of Pr on microstructure and electrical conductivity was discussed. It was showed that the material doped with Pr has a lot of dents and small openings, which provide channels for oxygen ions, resulting in lower grain boundary and total conductivity activation energy. Thus the corresponding grain boundary conductivity and total conductivity of the material were improved notably. The grain boundary conductivity of the material doped with Pr is 6.79×10^-3S·cm^-1 at 500 ℃, which is twice as large as that without Pr （5.61×10^-5S·cm^-1）.

同期刊论文项目
过渡金属化合物的合成及其特殊性质的研究
期刊论文 123 会议论文 4
过渡金属离子改性中温氧离子导体的设计合成及性能研究
期刊论文 41
同项目期刊论文
(Ce_(0.9)Nd_(0.1))_(1-x)Mo_xO_(2-δ)(0.00≤x≤0.10)的合成、表征与电性能(英文)
Hole doping double perovskites Sr2FeMo1-xO 6 (x = 0, 0.03, 0.04, 0.06) and their Mössbauer, cry
Mo掺杂对高纯Ce_(1-x)Nd_xO_(2-x/2)(x=0.10,0.15)体系烧结温度及晶界电性能的影响
新型氧离子导体La_(1.84)R_(0.16)Mo_(1.7)W_(0.3)O_(8.92)(R=Ca~(2+)、Sr~(2+)、Ba~(2+))的制备及其电性能
Structure and magnetic properties of new compounds CdYFeWO7
Preparation and electrical properties of new oxide ion conductors Ce 6-xGdxMoO15-δ (0.0&lex&le
Electronic and magnetic properties of the monoclinic phase BiCrO 3 from first-principles studies
Particle size-dependent charge ordering and magnetic properties in Pr 0.55Ca0.45MnO3
Preparation and electrical properties of new oxide ion conductors Ce6-xDyxMoO15-δ (0.0 &le x &
Synthesis, Characterization and Electrical Properties of (Ceo(0.9)Nd(0.1))(1-x)MoxO2-delta(0.00 <= x
Synthesis and Electrical Properties of New Solid State Electrolyte Materials Ce6-xHoxMoO15-delta(0.0
Nd~(3+)掺杂对LiFePO_4结构及电化学性能的改善
静电纺丝法制备LaFeO_3微纳米纤维
Mo的掺杂对Ce_(0.8)Gd_(0.2)O_(1.9)烧结温度及电性能的影响
Preparation of ferrite MFe2O4 (M = Co, Ni) ribbons with nanoporous structure and their magnetic prop
Preparation of one-dimensional CoFe2O4 nanostructures and their magnetic properties
Structural characterization, stability and electrical properties of strontium niobate ceramic
Hole doping double perovskites Sr2FeMo1-xO6 (x=0, 0.03, 0.04, 0.06) and their Mossbauer, crystal str
Structures and physical properties of n=3 Ruddlesden-Popper compounds Ca4Mn3-xNbxO10 (0 <= x <= 0.2)
Synthesis and characterization of (Zn,Cd)TiO3 by a modified sol-gel method
新型固体电解质Ce_(5.2)RE_(0.8)MoO_(15-δ)的合成及电性质
Pr掺杂对Ce_(5.2)Sm_(0.8)MoO_(15-δ)晶界及电性能的影响
Sm,Pr掺杂CeO_2和CeMoO_(15)基固体电解质的结构与性能
Structure and electrical properties of Pr ans Sm doped CeO2 and Ce2MoO15 based solid electrolytes
Synthesis and electrical properties of new solid state electrolyte materials Ce5.2RE0.8MoO15-δ
Preparation of CeO2-ZrO2 ceramic fibers by electrospinning
Grain boundary conductivity of high purity neodymium-doped ceria nanosystem with and without the dop
Structural and magnetic properties of Sr2Fe1-xGaxMoO6 (0 &le x &le 0.25)
Tunable synthesis, growth mechanism, and magnetic properties of La0.5Ba0.5MnO3
The magnetic and structural properties of hydrothermal-synthesized single-crystal Sn1-xFexO2 nanogra
机械活化放电等离子烧结制备Ce0.8Sm0.2O1.9固溶体
Fe_2O_3掺杂Ce_（0.8）Nd_（0.2）O_（1.9）固体电解质的结构与导电性能
Mo掺杂对高纯Ce1-xNdxO2-x/2（x=0.10,0.15）体系烧结温度及晶界电性能的影响
MgO掺杂Ce0.9Sm0.1O2-δ固体电解质的结构和电性能
静电纺丝法制备LaFeO3微纳米纤维
（Ce（0.9）Nd（0.1））（1-x）MoxO（2-δ）（0.00≤x≤0.10）的合成、表征与电性能
Sm，Pr掺杂CeO2和CeMoO15基固体电解质的结构与性能
新型氧离子导体La1.84R0.16Mo1.7W0.3O8.92（R=Ca^2＋、Sr^2＋、Ba^2＋）的制备及其电性能
Mn和Fe掺杂SnO2的水热合成与磁结构研究
Low temperature and hard mater
First-Principles Study on Diff
先驱体合成法制备PMN-PT弛豫铁电
水热法合成负热膨胀材料ZrW2O8
Grain boundary conductivity of
The improvement of low magneto
An investigation of low-field
Phase Behavior of BaLn2Mn2O7 (
Electrical Properties and Dila
Electron affinities and ioniza
Influence of Mn-O-Mn bond angl
Phase Behavior of Rare Earth M
Density functional study of Au
A novel organically templated
铅基弛豫铁电体陶瓷材料PMN-PT制
Magnetic and electronic proper
新型固体电解质Ce6-xSmxMoO15-y
Chemical bonding and electroni
Enhanced Thermal Stability of
Electronic structures of 4d tr
Theoretical study of transitio
Ferrimagnetic and half-metalli
Electronic structures of MCO (
Electronic structures of Al2W,
Cation?Ordering?in?the?Microwa
Neutron?diffraction?studies?of
Thermodynamic Properties of La
Density functional study of 3d
溶胶-凝胶法合成钛酸锌陶瓷粉体
Sol-gel synthesis of LaMO3 (M
Interaction of H2 with transit
Synthesis?and?Characterization
Geometries and electronic prop
Structural investigations on f
Density functional studies of
Molten Salt Synthesis of Lead
Nanocrystalline La2Mo2O9 and I
Electronic structures of 5d tr
熔盐法合成PbTiO3粉体及表征
High spontaneous polarization
Morphology controlled synthesi
A?Rapid?Synthesis?of?Multiferr
Hydrothermal?synthesis?of?sing
Tunable Synthesis, Growth Mech
Orbital ordering in Cs2AgF4 fr
4Trends in elasticity and elec
Facile?Alcohothermal?Synthesis
Crystal structure of microwave
Elastic and electronic propert
Geometries and electronic stru
Synthesis?of?Pr-doped?Ceria?Na
Structures and elastic propert
Electronic structures and chem
Density functional study of la
Nano-crystalline Synthesis and
Phase Evolution of Barium Tita
Thermal expansions of ceramics
Theoretical investigation of 5
A New Oxide Ion Conductor: La3
Facile Preparation of ZnTiO3 C
(Zn,M)TiO3(M=Co,Ni,Co0.5Ni0.5)
First principles comparative s
Charge ordering induced metal-
The magnetic and structure pro
Effect of Ti doping on magneti
Thermal expansion of lattice p
铁电陶瓷Pb1-xLaxTiO3的热膨胀性
Single Crystal growth of ZrW2O
Electronic structures of 3d-me
Electronic structures of hafni
Structural stability and elect
Thermal Expansion Properties o
Facile synthesis and photolumi
Study on Structure and oxide i
Ground state of lutetium dimer
Crystal structures and elastic
A New Family of Ce6MoO15 as fa
First-principles comparative s
a large low-field tunneling ma
Morphology-Controllable Synthe
Electronic properties of rheni
Magnetic properties and micros
Morphological Control and Lumi
Low-Temperature Synthe1sis and
Structure and Negative Thermal
Synthesis and thermoelectric p
熔盐法合成PbTiO3粉体及其表征
Mo掺杂对高纯Ce1-xNdxO2-x/2（x=0.10,0.15）体系烧结温度及晶界电性能的影响
Sm，Pr掺杂CeO2和CeMoO15基固体电解质的结构与性能
新型氧离子导体La1.84R0.16Mo1.7W0.3O8.92（R=Ca^2＋、Sr^2＋、Ba^2＋）的制备及其电性能
Mn和Fe掺杂SnO2的水热合成与磁结构研究
熔盐快速合成Pb1-xLaxTiO3粉体
熔盐法合成LiTaO3粉体
稀土Dy^3＋掺杂Fe3O4的合成及电磁性质
新型固体电解质Ce5．2RE0．8MoO15-δ的合成及电性质
晶体结构对化合物电学性质的影响
磁场下合成Fe3O4粉体的隧道磁阻
（Zn，M）TiO3（M=Co，Ni，Co0．5Ni0．5）固溶体的溶胶-凝胶法合成
A New Oxide Ion Conductor： La3GaMo2O12
期刊信息
  • 《化学学报》
  • 北大核心期刊（2014版）
  • 主管单位:中国科学院
  • 主办单位:中国化学会 中国科学院上海有机化学研究所
  • 主编：周其林
  • 地址：上海市零陵路345号
  • 邮编：200032
  • 邮箱：hxxb@sioc.ac.cn
  • 电话：021-54925085
  • 国际标准刊号：ISSN：0567-7351
  • 国内统一刊号：ISSN：31-1320/O6
  • 邮发代号:4-209
  • 获奖情况:
  • 首届国家期刊奖,第二届国家期刊奖提名奖,中国期刊方阵“双高期刊”
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘（网络版）,荷兰文摘与引文数据库,美国科学引文索引（扩展库）,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊（2004版）,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）,英国英国皇家化学学会文摘,中国北大核心期刊（2000版）
  • 被引量:28694