利用X射线光电子能谱仪分析研究了N80在不同配比的腐蚀溶液中形成膜的表面、一定深度的元素含量变化和缓蚀剂在N80表面作用的缓蚀机理。实验结果表明:曼尼希碱溶液与钨酸钠溶液复配使用,在N80表面形成了更致密的膜结构,能有效地减缓N80的腐蚀;且当钨酸钠浓度为0.0002mol/L,曼尼希碱浓度在0.0002~0.0200mol/L之间变化,配比为1:0.01时,N80表面C元素含量最多,N元素结合能最大,膜的厚度最厚,结构最稳定,缓蚀效率最好。
X-ray photoelectron spectroscopy(XPS) was used to analytically investigate the N80's surface film formed in the corrosive solution of different proportion and the element content' s change in a certain depth as well as the inhibition mechanism of corrosion inhibitor on N80' s surface. The experimental results show that, the Mannich base mixed with sodium tungstate solution can produce more compact film on the N80' s surface to retard any corrosion there; and when the concentration of sodium tungstate solution stays at 0. 000 2mol/L, that of Mannich base can range from 0. 000 2 to 0. 020 0mol/L; for a 1:0.01 solution proportion, the C ele- ment content on the N80' s surface becomes largest and the N element' s binding energy is the maximum to- gether with the thickest inhibitive film and the most stable structure as well as the highest inhibition efficiency.