重氮化合物在过渡金属催化剂作用下的分解以及后续反应在有机合成上得到了非常广泛的应用.综述了近年来钯催化重氮化合物反应的研究进展,主要包括环丙烷化反应、聚合反应、插入反应、交叉偶联反应及其机理的探讨.
Recent development in palladium-catalyzed reactions of diazo compounds including cyclopro- panation, polymerization, insertion reaction and cross-coupling reaction is reviewed. The mechanisms of these reactions are also discussed.