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炭/炭复合材料ZrB2改性硅基复合涂层的高温抗氧化性能
  • ISSN号：1003-6326
  • 期刊名称：《中国有色金属学报：英文版》
  • 时间：0
  • 分类：TG1[金属学及工艺—金属学]
  • 作者机构：[1]西北工业大学凝固技术国家重点实验室,西安710072
  • 相关基金：Projects（51221001,50972120）supported by the National Natural Science Foundation of China; Project（73-QP-2010）supported by the Research Fund of the State Key Laboratory of Solidification Processing of Northwestern Polytechnical University,China; Project（B08040）supported by Program of Introducing Talents of Discipline to Universities,China
作者： 李贺军[1], 姚西媛[1], 张雨雷[1], 姚栋嘉[1], 王少龙[1]
关键词： 炭, 炭复合材料, 涂层, ZRB2, 抗氧化性能, C/C composites, coating, ZrB2, anti-oxidation properties
中文摘要：

为提高硅基涂层的高温抗氧化性能,采用包埋法在炭/炭（C/C）复合材料表面制备ZrB2改性硅基涂层,研究涂层的相组成、微观形貌及其在1773、1873和1953K时的抗氧化性能。所制备的涂层结构致密,具有良好的抗氧化性能。在1773K下形成的稳定的ZrSiO4–SiO2氧化保护膜对C/C复合材料提供550h的氧化保护。涂层试样的抗氧化性能随温度的提高而降低,在1953K下氧化50h其质量损失为2.44%,这主要归因于ZrSiO4的高温分解和SiO2保护膜随温度升高的挥发。

英文摘要：

To improve the anti-oxidation ability of silicon-based coating for carbon/carbon （C/C） composites at high temperatures, a ZrB2 modified silicon-based multilayer oxidation protective coating was prepared by pack cementation. The phase composition, microstructure and oxidation resistance at 1773, 1873 and 1953 K in air were investigated. The prepared coating exhibits dense structure and good oxidation protective ability. Due to the formation of stable ZrSiO4-SiO2 compound, the coating can effectively protect C/C composites from oxidation at 1773 K for more than 550 h. The anti-oxidation performance decreases with the increase of oxidation temperature. The mass loss of coated sample is 2.44% after oxidation at 1953 K for 50 h, which is attributed to the decomposition of ZrSiO4 and the volatilization of SiO2 protection layer.

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期刊信息
  • 《中国有色金属学报：英文版》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:中国有色金属学会
  • 主编：黄伯云
  • 地址：中国长沙中南大学
  • 邮编：410083
  • 邮箱：f-xsxb@csu.edu.cn
  • 电话：0731-88830949
  • 国际标准刊号：ISSN：1003-6326
  • 国内统一刊号：ISSN：43-1239/TG
  • 邮发代号:42-317
  • 获奖情况:
  • 国家“双百”期刊,第二届全国优秀科技期刊评比二等奖,中国有色金属工业总公司优秀科技期刊一等奖
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  • 被引量:1159