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Mn2O3单晶的合成、结构表征及磁性研究
  • ISSN号：0251-0790
  • 期刊名称：《高等学校化学学报》
  • 时间：0
  • 分类：O614[理学—无机化学;理学—化学]
  • 作者机构：[1]吉林大学无机合成与制备化学国家重点实验室,长春130012
  • 相关基金：国家自然科学基金（批准号：20471022,40673051和20121103）资助.
作者： 王晓峰[1], 李光华[1], 褚清新[1], 刘晓旸[1], 冯守华[1]
关键词： 助熔剂法, 三氧化二锰, 晶体结构, 磁性, Flux method , Dimanganese trioxide , Crystal structure , Magnetism
中文摘要：

锰氧化物以其多样的电学、磁学及催化等方面的特性而受到人们广泛的关注，但目前对其研究主要集中在粉末或纳米尺度晶体的合成与性质方面．以Mn2O3为例，其作为催化剂被广泛应用于一氧化碳和有机污染物的氧化催化以及氮氧化物的还原反应中，同时也是Li—Mn-O氧化物电极材料重要的基底材料.关于Mn2O3纳米材料的合成已有大量报道，但却很少涉及其大晶体合成的研究．

英文摘要：

Dimanganese trioxide waste gas as an important one of is an active catalyst for removing carbon manganese oxides. Its single crystal was crystal X-ray diffraction reveals that the compound crystallized in the monooxide and nitrogen oxide from synthesized by flux method. Single cubic space group Ia-3 with a = 0. 94173（11） nm, V=0. 83518（17） nm^3, Z=48, Dc =5.022 Mg/m^3, R（int） =0. 0863, R1 =0.0659[I〉 2σ（I） ], wR2 =0. 1929[I〉2σ（I）].

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期刊信息
  • 《高等学校化学学报》
  • 北大核心期刊（2011版）
  • 主管单位:中华人民共和国教育部
  • 主办单位:吉林大学 南开大学
  • 主编：周其凤
  • 地址：吉林大学南胡校区
  • 邮编：130012
  • 邮箱：cjcu@jlu.edu.cn
  • 电话：0431-88499216
  • 国际标准刊号：ISSN：0251-0790
  • 国内统一刊号：ISSN：22-1131/O6
  • 邮发代号:12-40
  • 获奖情况:
  • 首届及第二届国家期刊奖,连续两届“百种中国杰出学术期刊”,中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘（网络版）,荷兰文摘与引文数据库,美国工程索引,美国科学引文索引（扩展库）,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊（2004版）,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）,英国英国皇家化学学会文摘,中国北大核心期刊（2000版）
  • 被引量:50676