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温度对活性污泥胞外聚合物组分的影响研究
  • ISSN号:0367-6234
  • 期刊名称:《哈尔滨工业大学学报》
  • 时间:0
  • 分类:X703[环境科学与工程—环境工程]
  • 作者机构:[1]深圳大学化学与化工学院,广东深圳518060, [2]哈尔滨工业大学市政环境工程学院,哈尔滨150090
  • 相关基金:国家自然科学基金资助项目(50578053)
中文摘要:

将SiC及污泥本身的热解固体残留物分别添加到污泥中,实现污泥在微波场中的快速升温及高温热解,并对其液、气、固3态产物的特性及再利用价值加以分析。实验表明:添加SiC及固体残留物的污泥微波高温热解液态产物的热值可以达到37MJ/kg以上,多环芳烃(PAHs)含量低于5.37%;气态产物中H2和CO的体积分数在54%以上,热值达到9420kJ/m^2;添加热解固体残留物的污泥微波热船固态产物的比表面积达到305m^2/g。污泥微波热解产物的特性为其用作燃料和吸附剂提供了可能。

英文摘要:

The objective of this paper is to investigate the features of the solid, liquid and gas yields from the pyrolysis of sewage sludge with microwave as heating source and then evaluate their quality. To achieve high temperature and rapid heating speed, SiC and char produced by the sludge pyrolysis were used as microwave absorbers, respectively. Microwave absorbers mixed with the sewage sludge before pyrolysis were varied so that their influence on the characteristics of the resulting gases, liquids and solid residues could be studied. It could be determined from the result of experiment that the heating value of the liquid can reach 37 MJ/kg, and the content PAHs was less than 5.37 %. The use of microwave heating in pyrolysis of sewage sludge produced liquid that had less environmental and toxicological impact. The volume proportion of H2 and CO in the gases was higher than 54 %, and the heating values of the gases were higher than 9 420 kJ/m^2. Microwave pyrolysis had a significant convenience on the formation of H2 and CO. Furthermore, syngas (H2 and CO) can be produced in a high yield from the microwave pyrolysis of sewage sludge with the assistance of microwave absorber. The SBET of the solid produced by microwave pyrolysis of sewage sludge with char as absorber can reach 305 m2/g, which is higher than the microwave pyrolysis with SiC as absorber. The high BET specific surface area of solid are suitable for them to be upgraded as sorbent. Both oils and gases produced in the pyrolysis showed relatively high overall heating values, comparable to some conventional fuels, revealing the potential application of these products as fuel.

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期刊信息
  • 《哈尔滨工业大学学报》
  • 中国科技核心期刊
  • 主管单位:中华人民共和国工业和信息化部
  • 主办单位:哈尔滨工业大学
  • 主编:冷劲松
  • 地址:哈尔滨市南岗区西大直街92号
  • 邮编:150001
  • 邮箱:
  • 电话:0451-86403427 86414135
  • 国际标准刊号:ISSN:0367-6234
  • 国内统一刊号:ISSN:23-1235/T
  • 邮发代号:14-67
  • 获奖情况:
  • 2000年获黑龙省科技期刊评比一等奖,中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),美国数学评论(网络版),德国数学文摘,荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:27329