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生物可降解有机配体EDDS等对土壤外源重金属的植物富集效应研究
  • ISSN号:1672-2043
  • 期刊名称:农业环境科学学报
  • 时间:0
  • 页码:458-461
  • 语言:中文
  • 分类:S154.4[农业科学—土壤学;农业科学—农业基础科学]
  • 作者机构:[1]南京工业大学城建与安全环境学院,江苏南京210009, [2]南京大学现代分析中心,江苏南京210093
  • 相关基金:污染控制与资源研究国家重点实验室开放研究基金(PCRRF06001);国家自然科学基金(20607010)
  • 相关项目:污染土壤淋洗修复有机配体筛选及其去除污染物的机理研究
作者: 丁竹红|胡忻|
中文摘要:

通过小麦的盆栽实验研究了生物可降解有机配体EDDS、柠檬酸和半胱氨酸在5mmol·kg^-1浓度下对土壤中重金属Cu、Cd、Pb和Zn的植物富集的影响,同时采用0.1mol·L^-1 HAc提取元素可交换态含量与植物实验相对照。结果发现,在所试验的外源土壤金属浓度下.EDDS处理对所研究的金属在小麦幼苗体内的富集和它们在小麦幼苗体内的传输有明显的诱导作用。EDDS处理组的小麦根和茎叶金属含量均高于对照组。EDDS处理组Cd、Cu、Zn和Pb的茎叶富集系数(分别为0.209、0.640、0.339和0.726)远高于对照组Cd、Cu、Zn和Pb的茎叶富集系数(分别为0.059、0.071、0.046和0.353)。柠檬酸处理和半胱氨酸处理对Cu、Zn和Pb的茎叶富集系数影响不大,但明显提高了Cd的茎叶富集系数(分别为0.118和0.115)。添加EDDS后土壤中4种重金属的可交换态含量增加最明显。半胱氨酸对可交换态含量影响不明显,这与小麦体内富集的金属含量趋势相一致。对于不同的金属而言,Cd的根系相对富集量比较高.可达外源添加浓度的2.46倍(EDDS处理组),其可交换态的相对含量也最高,可达外源添加浓度的68.6%-96.9%。Pb的植物富集效率和可交换态含量较低。

英文摘要:

The effects of biodegradable organic ligands such as [s,s']-ethylenediamine disuccinic acid (EDDS), citric acids and cysteine on the phyto-concentration of four heavy metals (Cu, Cd, Pb, Zn) in sandy soil were investigated using pet experiment of wheat seedlings. 5 mmol ·kg^-1 EDDS, citric acids and cysteine were added respectively. The phytoextraction of the four metals were also assessed by their fractions extracted by 0.1 mol· L^-1 HAc. The results showed that the addition of 5 mmol· kg^-1 EDDS greatly induced the concentration and transposition of the investigated metals in wheat seedlings. Shoot concentration factors of the seedlings treated by EDDS (0.209, 0.640, 0.339 and 0.726 respectively) were greatly higher than that of the control (0.059, 0.071, 0.046 and 0.353 respectively). Citric acids and cysteine only had slight effects on the shoot concentration factors of Cu, Zn and Pb, but greatly improved that of Cd (0.118 and 0.115 respectively), The fractions of the four metals extracted by 0.1 mol· L^-1 HAc in the soils after cultivation increased significantly under the treatment of EDDS, but the addition of cysteine had little effects. The performance was corresponding with the results gained in pot experiment. Among the four metals, the root concentration of Cd was the highest, 2.46 times of the spiked concentration in the treatment of EDDS. The fraction of Cd extracted by 0.1 mol ·L^-1 HAc was also the highest, 68.6%-96.9% of the spiked concentration in the soils. The lowest uptake and fraction extracted by 0.1 mol· L^-1 HAc were found in all treatments with lead except shoot concentration in EDDS treatment.

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期刊信息
  • 《农业环境科学学报》
  • 北大核心期刊(2011版)
  • 主管单位:中华人民共和国农业部
  • 主办单位:农业部环境保护科研监测所 中国农业生态环境保护协会
  • 主编:李文华
  • 地址:天津市南开区复康路31号
  • 邮编:300191
  • 邮箱:caep@vip.163.com
  • 电话:022-23674336 23006209
  • 国际标准刊号:ISSN:1672-2043
  • 国内统一刊号:ISSN:12-1347/S
  • 邮发代号:6-64
  • 获奖情况:
  • 全国中文核心期刊,列于被引频比最高的中国科技期刊500名之内
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),英国农业与生物科学研究中心文摘,美国剑桥科学文摘,中国中国科技核心期刊,中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:34877