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Hastelloy C-276/316L激光异质焊焊缝腐蚀性能
  • ISSN号:1004-0609
  • 期刊名称:中国有色金属学报
  • 时间:2014.2.15
  • 页码:441-447
  • 分类:TG404[金属学及工艺—焊接]
  • 作者机构:[1]大连理工大学精密与特种加工教育部重点实验室,大连116024
  • 相关基金:国家重点基础研究发展计划资助项目(2009CB724307); 国家自然科学基金资助项目(51175061)
  • 相关项目:陶瓷结构件双激光束低应力近净成形机理与方法研究
中文摘要:

利用连续激光对Hastelloy C-276和316L进行焊接,借助电化学腐蚀方法比较焊缝中心附近和母材在酸性、中性、碱性溶液中的腐蚀性能,并利用扫描电子显微镜和X线能量色散谱分析腐蚀形貌以及腐蚀表面元素成分。结果表明:在酸性环境中,抗腐蚀性由大到小的顺序为C-276的抗腐蚀性、焊缝、316L;在中性环境中,焊缝的抗腐蚀性和母材的相似;而在碱性环境中,焊缝的抗蚀性优于316L的,而其腐蚀趋势大于C-276的,但腐蚀速率小于C-276的;C-276中Mo元素较316L中的多,认为焊缝中Mo元素主要来自C-276,而Mo元素在焊缝枝晶间、枝晶杆的含量差别是造成焊缝在酸性、中性溶液中枝晶间腐蚀的重要原因之一;在碱性溶液中焊缝发生点蚀,这与晶格缺陷有关。

英文摘要:

By using continuous laser to weld Hastelloy C-276 and 316L and method of electrochemical corrosion, the corrosion resistances of the weld and base material in acid, neutral and alkaline solution were studied, continuously. The corrosion morphology and the composition of the corrosion surface were analyzed by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). The results show that, in the acidic environment, the sequence of corrosion resistance from high to low are C-276, weld, 316L. In the neutral environment, there is little difference between corrosion resistance of the weld and base materials. In the alkaline environment, the corrosion tendency of 316L is the largest, corrosion tendency of the weld follows, the corrosion tendency of C-276 is the minimum. While the corrosion speed of weld and 316L has no obvious difference, and both of them are obviously less than C-276. In the acidic and neutral solution,the intergranular corrosion is found in the weld. The mass fraction of Mo in the intergranular is about 4%larger than that in the grain. This shows that the segregation of Mo element has a great influence on intergranular corrosion. In the alkaline solution, pitting corrosion is found in the weld and it is associated with lattice defects.

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期刊信息
  • 《中国有色金属学报》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:中国有色金属学会
  • 主编:黄伯云
  • 地址:湖南省长沙市中南大学内
  • 邮编:410083
  • 邮箱:f-ysxb@csu.edu.cn
  • 电话:0731-88876765 88877197
  • 国际标准刊号:ISSN:1004-0609
  • 国内统一刊号:ISSN:43-1238/TG
  • 邮发代号:42-218
  • 获奖情况:
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,英国科学文摘数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:33974