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防火涂层材料研究及产业化中的关键技术开发的研究进展
  • 期刊名称:厦门大学学报(自然科学版)
  • 时间:0
  • 页码:365-377
  • 语言:中文
  • 分类:TQ635[化学工程—精细化工]
  • 作者机构:[1]厦门大学材料学院,福建省防火阻燃材料重点实验室,福建省固体表面涂层材料技术开发基地,福建厦门361005
  • 相关基金:国家自然科学基金(50873082); 福建省重大科技平台建设基金(2009J1009); 福建省产学重大专项(2010H6021); 福建省科技重点项目(2007T0013 2008H0033); 福建省自然科学基金项目(2010J01306); 福建省产学研联合开发(省属)专项(闽经贸计财[2009]602号); 福建省省级工商发展资金(闽经贸计财[2010]691号); 厦门市科技项目(3502Z20031078 3502Z20041054 3502Z20070010 3502Z20073006 3502Z20081045 3502Z20103004)
  • 相关项目:POSS基高分子拓扑结构设计/纳米构筑杂化环氧树脂的相行为研究
作者: 戴李宗|
中文摘要:

综述了近年来钢结构建筑防火涂料、隧道防火涂料领域的国内外研究进展,重点叙述了本课题组在该领域近10年来取得的研究成果和产业化情况.在防火涂层材料的研究中,本课题组凝练出以下关键技术:功能性填料复配技术,提高功能组分的协同作用;功能性填充料的表面处理技术,解决了涂料相结构稳定性和膨胀炭层强度、均匀性、膨胀倍率等制约涂层防火性能的关键技术;聚合物/层状硅酸盐纳米插层技术在隧道防火涂料领域的首次应用;聚合物粘结剂和无机凝胶材料复配技术,提高涂层粘结性能的高温连续性,改善涂层耐水性、柔韧性;复合纤维自替代技术,实现耐火性能的连续性;超细活性粉料低温烧结技术,使涂层在较宽的温度下烧结形成陶瓷面(体),极大地提高了涂层高温下的强度和耐火性能.

英文摘要:

In this paper,recent research progress in fire-retardant coating for(super) high-rise steel structure building and tunnel was reviewed.The recent 10 years′ research on these two aspects of authors′ group and its industrialization were introduced in detail.In the industrialization of fire-retardant materials,we used a series of key technologies as follows:surface treatment and synergistic technology of functional fillers and its synergistic effect,which improved the key factors that limit the fire-retardance,such as structural stability,intensity,uniformity,and intumescent multiplying power of intumescent char configuration;polymer/montmorillonite(MMT) nanocomposites prepared by intercalated technology were first utilized in tunnel fire retardant coating;the continuing adhesion at high temperature,waterproof,flexibility of coating were improved by synergistic technology of polymer and silicate binders;the continuing fire retardance of coating was realized via self-replacing of compound fibers;sintering technics at low temperature of superfine active power made ceramic surface form under a wide range of temperature,which enhanced the intensity and retardance of coating tremendously.

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