报道了一种新的上转换发光材料X2型Y2SiO5:Er,Yb并研究了Yb^3+浓度和泵浦功率对样品的上转换发光特性的影响:(1)随着Yb^3+浓度的增加,绿、红光发射均呈先增强后减弱的变化,但相对于绿光发射,红光发射受Yb^3+浓度的影响更剧烈,并且当12%(摩尔分数)Yb^3+时,可以得到很纯的红光发射;(2)上转换发光强度与泵浦功率的关系表明,双光子吸收贡献样品的上转换发射。此外,讨论了可能的上转换机制。认为随着Yb^3+浓度增加,Er^3+的激发态吸收、Yb^3+到Er^3+的能量传递和Er^3+的交叉弛豫对上转换发光的作用依次逐渐加强。
In this paper, a new upconversion luminescence material X2 type Y2SiO5: Yb, Er was reported. The upconversion luminescent properties as a function of Yb^3+ concentration and pumping power were were studied. (1)As Yb^3+ concentration increased, both the green and red light increased first, and then decreased. Howev- er, compared with the green light emission, the red depended on Yb^3+ concentration more strongly, and pure red light emission was obtained when Yb^3+ concentration was 12mol%. (2)The relationship between the upeonversion intensity and pumping power indicated that the upconversion emission based on two-photon absorption. Moreover the mechanisms of upconversion luminescence were studied. It was considerered that as Yb^3+ concentration increased, the effects of the excited state absorption of Er^3+ , energy transfer from Yb^3+ to Er^3+ and cross-relaxation of Er^3+ on the upconversion luminescence gradually enhanced in turn.