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LY12铝合金阳极氧化膜受热后的开裂及其对腐蚀电化学行为的影响
  • ISSN号:1000-7857
  • 期刊名称:《科技导报》
  • 时间:0
  • 分类:TG146.21[金属学及工艺—金属材料;一般工业技术—材料科学与工程;金属学及工艺—金属学]
  • 作者机构:[1]北京化工大学材料科学与工程学院,北京100029
  • 相关基金:国家自然科学基金项目(50571006)
中文摘要:

用扫描电子显微镜和电化学方法研究了LY12合金阳极氧化膜受热开裂行为和开裂前后的电化学行为。LY12铝合金阳极氧化膜经沸水封闭后存在网络状非穿透性微裂纹;加热后,裂纹在热应力作用下拓宽并发展成穿透性裂纹。引入了裂纹密度(单位面积上的裂纹总长度)和开裂部分所占的面积比来定量表征氧化膜的开裂程度。氧化膜受热开裂以后,其保护性能显著降低,极化电流增大而阻抗值明显降低;氧化膜耐蚀性的变化与裂纹面积比有关,裂纹面积比增大,阻抗与耐蚀性降低。

英文摘要:

The cracking and electrochemical behaviors of anodic film of LY12 alloy after being heated at 300℃ were investigated by scanning electron microscopy and electrochemical methods. The results show that some micro-cracks were formed in the sealed anodic films of the alloy before being heated. After being heated at 300℃, the crack density kept almost unchanged but the initial micro-cracks became wider and deeper and might penetrate through the film. Partial abruptions occurred on the oxide/metal interface The ratio of cracked part of substrate covered by anodic film to the total area was employed to represent the electrolyte penetration through the barrier layer in attacking the substrate. The cracking of films resulted in a decrease of the film resistance and an increase of the corrosion current density. Corrosion resistance of the film was related to the ratio of cracked area to the total area. The polarization current density was hardly affected by the ratio. But at a relatively high polarization potential, the film resistance was decreased and the corrosion rate was increased as the ratio was increased.

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期刊信息
  • 《科技导报》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学技术协会
  • 主办单位:中国科学技术协会
  • 主编:项昌乐
  • 地址:北京市海淀区学院南路86号科技导报社
  • 邮编:100081
  • 邮箱:kjdbbjb@cast.org.cn
  • 电话:010-62138113
  • 国际标准刊号:ISSN:1000-7857
  • 国内统一刊号:ISSN:11-1421/N
  • 邮发代号:2-872
  • 获奖情况:
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),英国农业与生物科学研究中心文摘,波兰哥白尼索引,美国乌利希期刊指南,美国剑桥科学文摘,英国科学文摘数据库,中国中国科技核心期刊,中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:24858