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中文摘要：
以MCM-48为载体，通过浸渍法制备了H6P2W18O62/MCM-48催化剂，并采用FT-IR、XRD、SEM、EDS对催化剂进行表征。以微波促进30%（质量分数）H2O2氧化环己酮合成己二酸反应为探针，考察了H6P2W18O62/MCM-48的催化性能，并通过正交实验确定了优化的工艺条件。结果表明，采用H6P2W18O62负载量40%的H6P2W18O62/MCM-48催化剂，在优化的合成己二酸的工艺条件下，即催化剂质量分数（以环己酮质量计）5.1%、n（C6H10O）∶n（H2O2）∶n（H2C2O4·2H2O） = 100∶450∶1.88、反应温度95℃、微波功率300 W、反应时间3.5 h，己二酸收率可达81.3%；催化剂重复使用5次，己二酸收率仍可达到64.6%。
英文摘要：
Dawson structure phosphotungstic acid supported on MCM-48 was prepared by impregnation method and characterized by FT-IR, XRD, SEM and EDS. The synthesis of adipic acid with cyclohexanone and 30% hydrogen peroxide under microwave irradiation was carried out as a probe reaction to study the catalytic activity of H6P2W18O62/MCM-48.The main reaction conditions were optimized with orthogonal experiments. The results showed that with 40% H6P2W18O62/MCM-48 as catalyst, under the optimal conditions of the catalyst to cyclohexanone mass ratio of 5.1%, n（C6H10O）∶n（H2O2）∶ n（H2C2O4·2H2O）=100∶450∶1.88, the reaction temperature of 95℃, microwave power of 300 W, irradiation time of 3.5 h, the isolated yield of adipic acid could reach 81.3%, and the catalyst could be reused five times with the isolated yield of adipic acid still above 64.6%.
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同项目期刊论文
Clean Oxidation of Cyclohexanone to Adipic Acid Catalyzed by Ammonium Phosphomolybdate with Dawson s
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