采用磁控溅射沉积方法制备Mg2Si半导体薄膜。首先在Si衬底上沉积Mg膜,随后低真空热处理。采用X射线衍射、扫描电镜、拉曼光谱对Mg2Si薄膜的结构进行表征。研究了在低真空(10-1~10-2Pa)条件下热处理温度(350~550℃)和热处理时间(3~7h)对Mg2Si薄膜形成的影响。结果表明,低真空热处理条件下制备了单一相Mg2Si半导体薄膜,400~550℃热处理4~5h是最佳的热处理条件。在拉曼谱中256和690cm-1处观察到两个散射峰,这与Mg2Si的拉曼特征峰峰位一致。
Semiconducting Mg2Si films were prepared by magnetron sputtering,Mg film was deposited onto Si substrate and subsequent low vacuum heat treatment was carried out.X-ray diffraction,scanning electron microscopy and Raman spectra were performed to characterize and analyze the structure of films.Effects of heat treatment temperatures(350-550℃) and heat treatment time(3-7 h) on the formation of Mg2Si films were investigated under low vacuum(10-1-10-2Pa).The results show that the optimal heat treatment conditions for preparing single phase Mg2Si film are 400-550℃ and 4-5h in low vacuum.Two distinguished peaks at 256 and 690cm-1 are observed in Raman scattering spectra,which are characteristic peak position of Mg2Si.