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高温地热流体来源氟在环境中的分布特征——以西藏羊八井热田为例
  • ISSN号:1000-2251
  • 期刊名称:《东华理工大学学报:自然科学版》
  • 时间:0
  • 分类:TK521[动力工程及工程热物理—热能工程]
  • 作者机构:[1]中国地质大学环境学院,湖北武汉430074
  • 相关基金:基金项目:国家自然科学基金项目(40702041);高等学校博士学科点专项科研基金项目(20070491008);中国博士后科学基金特别资助项目;中国博士后科学基金项目(20080430146);“地质过程与矿产资源”国家重点实验室开放基金资助项目(GPMR200714)的资助
中文摘要:

西藏羊八井地热电厂产生的高氟废水直接排入了流经羊八井热田的藏布曲(河)。利用离子色谱仪(IC)测定了藏布曲水样的氟浓度;通过浸提实验提取了藏布曲河床沉积物中的总氟和各种存在形态的氟,并确定了其含量。藏布曲河水的氟浓度明显受到地热废水排放的影响,河床沉积物中水溶态氟和可交换态氟的分布也与地热电厂排污口的位置有明显的对应关系。然而,河床沉积物中的铁锰结合态氟、有机束缚态氟、残余态氟和总氟的分布与地热废水排放无显著联系,表明地热废水来源氟在进入藏布曲后主要向河床沉积物中的水溶态氟和可交换态氟转化。藏布曲河床沉积物是地热废水来源氟的一个汇。

英文摘要:

The high-fluoride wastewaters generated by the Yangbajing geothermal power plant in Tibet, Which were discharged directly into the Zangbo River that flows across the Yangbajing geothermal field. The fluoride concentrations of all water samples collected from the Zangbo River were determined using ion chromatograph ( IC), and the total fluoride (Total-F), water soluble fluoride, exchangeable fluoride, fluoride bound to Fe/Mn oxides, fluoride bound to organic matter and residual fluoride in all riverbed sediment samples were extracted with sequential chemical extraction procedure and then their concentrations were measured. The fluoride concentration in the Zangbo River water was evidently affected by the geothermal wastewater discharge. The distribution of water soluble fluoride and exchangeable fluoride in the riverbed sediments matches well with the locations of geothermal wastewater outlets. However, there is no obvious correspondence between the locations of the wastewater outlets and the concentrations of fluoride bound to Fe/Mn oxides, fluoride bound to organic matter, residual fluoride and total fluoride in riverbed sediments, indicating that the fluoride with geothermal wastewater source was mainly transformed into water soluble fluoride and exchangeable fluoride in sediments after it was discharged into the Zangbo River. The riverbed sediment is a sink of fluoride from geothermal wastewater.

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期刊信息
  • 《东华理工大学学报:自然科学版》
  • 中国科技核心期刊
  • 主管单位:江西省教育厅
  • 主办单位:东华理工大学
  • 主编:胡宝群
  • 地址:江西省抚州市学府路56号
  • 邮编:344000
  • 邮箱:ecutxb@163.com
  • 电话:0794-8258317
  • 国际标准刊号:ISSN:1000-2251
  • 国内统一刊号:ISSN:36-1273/N
  • 邮发代号:
  • 获奖情况:
  • 1989年获全国高校自然科学学报质量评比三等奖,1992年获江西省先进期刊奖 1993年获江西省先进科...,1995年获全国高校自然科学学报质量评比二等奖
  • 国内外数据库收录:
  • 美国化学文摘(网络版),中国中国科技核心期刊
  • 被引量:1521