采用溶液燃烧合成Mg2+掺杂LaFeO3超细粉体,并利用XRD、SEM、BET和UV-VIS分析Mg2+掺杂量对合成粉体的物相组成、微观形貌和光催化性能的影响。结果表明:Mg2+取代Fe3+形成LaFe1-xMgxO3(0≤x≤0.2)有限型固溶体。当掺杂量为0.1时(x=0.1),合成粉体具有最大的比表面积(43.46m2/g)和较小粒径(径向和长度方向分别为100nm和150nm),因此具有最佳的光催化性能,在高压汞灯180min照射下,对甲基橙溶液(10mg/L)的降解率达75.2%,与纯LaFeO3的相比,光降解率增加26.5%,且光催化反应符合一级动力学方程。
Mg2+ doped La Fe O3 ultrafine powders were synthesized by solution combustion method. Effects of Mg2+ doping content on phase composition, microstructure and photocatalytic performances of the synthesized powders were investigated by XRD, SEM, BET, and UV-Vis. The results show that Mg2+ substitutes for Fe3+ to form La Fe1-xMgxO3(0≤x≤0.2) limited solid solution. When Mg2+ doping content is 0.1, La Fe0.9Mg0.1O3 powder has a maximum specific surface area(43.46 m2/g) and smaller particle size(100 nm and 150 nm in diameter and length direction, respectively). It has the best photocatalytic ability with photodegradation efficiency of 75.2% to methyl orange(10 mg/L) under high-pressure mercury lamp irradiation for 180 min. It increases 26.5% than that of the pure LaF eO 3 under the same experimental conditions, and the reaction may be described as the pseudo first order kinetics equation.