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中文摘要：
以2，2＇-二溴-5，5＇-二（三甲硅基）-[3，3’]联噻吩为原料，在无水无氧低温条件下制备出一种新的十元大环低聚噻吩化合物，并用核磁共振、红外光谱以及高分辨质谱对其结构进行了表征．X射线单晶衍射分析确定了其晶体属于单斜晶系，C2／c空间群，分子中心为十元大环结构呈“扭船型”构象，平均内径约为0．3970nm．
英文摘要：
The ten-membered macrocyclic oligothiophene compound was synthesized using 2, 2＇-dibromo-5, 5＇-bistrimethylsilanyl-[3,3＇] bithiophenyl as raw material via moisture sensitive reaction at low temperature. The title compound was characterized by ^1H NMR, ^13C NMR, FT-IR, HRMS and X ray single crystal analysis. The crystal structure of title compound belongs to monoclinic, space group C2/c. The central ten-membered ring shows a ‘twist boat＇ form with average inner diameter of 0. 397 0 nm.
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