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Carbon and hydrogen isotopic composition and generation pathway of biogenic gas in China
  • ISSN号:1000-9426
  • 期刊名称:Chinese Journal of Geochemistry
  • 时间:0
  • 页码:119-124
  • 语言:英文
  • 分类:P736.211[天文地球—海洋地质;天文地球—海洋科学] P618.130.1[天文地球—矿床学;天文地球—地质学]
  • 作者机构:[1]The Key Laboratory of Gas Geochemistry, Chinese Academy of Sciences, Lanzhou 730000, China
  • 相关基金:Acknowledgements The research was supported by the National Natural Science Foundation of China (Grant No. 40703001).
  • 相关项目:水在气态烃形成中作用的氢同位素示踪
中文摘要:

碳和氢源於生物的气体的同位素的作文为它的产生小径和 reservoiring 特征的学习是很重要的。在这篇论文,在中国的源於生物的煤气的水库的形成小径和 reservoiring 特征以碳和氢被描述从 10 座源於生物的煤气的水库的 31 件煤气的样品的同位素的作文。学习表演氢这些源於生物的煤气的水库的同位素的作文能被划分成三间隔:δ】−200 ‰, −250 ‰ & lt; δ【-−200 ‰和 δ【−250 ‰。先进相信在新鲜的水是的大陆人的条件下面的源於生物的气体的主要产生小径醋性的发酵。我们的研究结果证明在海洋的外形的条件下面的源於生物的气体的产生小径是典型公司 2- 减小,源於生物的气体有重氢同位素的作文:它的 δ 价值比 −200 ‰高;在大陆人外形的条件下面的源於生物的气体被一样的方法,而是它的氢也产生同位素的作文比简历,基因气体在典型海洋的外形状况下面产生了轻:−250 ‰ & lt; δ【−200 ‰, δ 价值可能与在古老的湖的水媒介的咸度有关。从 Qaidam 盆的相关数据,这能被看见源於生物的甲烷的同位素的作文有的氢有增加水的咸度的一样的变化趋势中等。有源於生物的煤气的水库,在大陆人外形的条件下面在过渡区域形成。这些煤气的水库是源于公司 2-reduction 和醋性的发酵,其形成可能与中等的古老的水和相对高的地热的坡度的非变体的咸度有关,盒子在 Baoshan 盆被遇到。在这些区域产生的源於生物的气体有轻氢同位素的作文:δ【−250 ‰,和相对重的碳同位素的作文。在碳之间有相当强壮的否定关联同位素的作文和氢同位素的作文。产生机制和碳的小径,和氢源於生物的气体的同位素的作文可以被用来查明从自然界的源於生物的煤气的样品是否具有?

英文摘要:

The carbon and hydrogen isotopic composition of biogenic gas is of great importance for the study of its generation pathway and reservoiring characteristics. In this paper, the formation pathways and reservoiring characteristics of biogenic gas reservoirs in China are described in terms of the carbon and hydrogen isotopic compositions of 31 gas samples from 10 biogenic gas reservoirs. The study shows that the hydrogen isotopic compositions of these biogenic gas reservoirs can be divided into three intervals: 6DCH4〉-200‰, -250‰〈δDCH4〈-20‰ and δDCH4〈-250‰. The forerunners believed that the main generation pathway of biogenic gas under the condition of continental fresh water is acetic fermentation. Our research results showed that the generation pathway of biogenic gas under the condition of marine facies is typical CO2- reduction, the biogenic gas has heavy hydrogen isotopic composition: its δDCH4 values are higher than -200‰; that the biogenic gas under the condition of continental facies also was generated by the same way, but its hydrogen isotopic composition is lighter than that of biogenetic gas generated under typical marine facies condition: -250‰〈δDCH4〈-200‰, the δDCH4 values may be related to the salinity of the water medium in ancient lakes. From the relevant data of the Qaidam Basin, it can be seen that the hydrogen isotopic composition of biogenic methane has the same variation trend with increasing salinity of water medium. There are biogenic gas reservoirs formed in transitional regions under the condition of continental facies. These gas reservoirs resulted from both CO2- reduction and acetic fermentation, the formation of which may be related to the non-variant salinity of ancient water medium and the relatively high geothermal gradient, as is the case encountered in the Baoshan Basin. The biogenic gas generating in these regions has light hydrogen isotopic composition: δDCH4〈-250‰, and relatively heavy carbon isotopic composition. There is a fairly stron

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