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基于Friedel-Crafts反应的3-吲哚取代苯硼唑的水相合成
  • ISSN号：0253-2786
  • 期刊名称：有机化学
  • 时间：2014.11
  • 页码：2456-2461
  • 分类：G64[文化科学—高等教育学;文化科学—教育学] O6[理学—化学]
  • 作者机构：[1]复旦大学化学系,上海200433, [2]复旦大学先进材料实验室,上海200438
  • 相关基金：国家自然科学基金（21103023）
  • 相关项目：复旦大学化学基地
作者： 张慧明|沈少春|杨笑迪|孙兴文|
关键词： 绝对构型, 理论与计算化学, 电子圆二色谱, 振动圆二色谱, 旋光光谱, Absolute configuration, Theoretical and computational chemistry, Electronic circulardichroism, Vibrational circulardichroism, Optical rotatory dispersion
中文摘要：

手性化合物的结构确定，尤其是新型手性化合物的绝对构型测定一直是不对称研究的重要工作。除单晶测试外，光谱学方法近年来被广泛应用于手性分子结构鉴定，主要包括电子和振动圆二色谱、旋光光谱、旋光拉曼谱等。本文对上述测试方法的原理、应用范围和相关理论计算方法做了介绍。把谱学测试与理论计算相结合，将成为手性分子结构鉴定的重要发展方向。

英文摘要：

The determination of the absolute configuration （AC） of chiral compounds, especially the new chiral compounds, is one of the difficulties of the structure determination. The most widely used AC determination chiroptical spectroscopic methods include electronic and vibrational circular dichroism, optical rotatory dispersion, Raman optical activity etc. This mini review summarizes the main test principles, applications and corresponding theoretical calculation methods. With the developments of theoretical chemistry, the AC determination through instrumental characterization technique coupled with quantum chemical calculation, is envisaged to be the new trends of AC assignment.

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期刊信息
  • 《有机化学》
  • 中国科技核心期刊
  • 主管单位:
  • 主办单位:中国化学会 中国科学院上海有机化学研究所
  • 主编：陈庆云
  • 地址：上海市枫林路354号
  • 邮编：200032
  • 邮箱：bianji@mail.sioc.ac.cn
  • 电话：021-54925244
  • 国际标准刊号：ISSN：0253-2786
  • 国内统一刊号：ISSN：31-1321/O6
  • 邮发代号:4-285
  • 获奖情况:
  • 中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘（网络版）,荷兰文摘与引文数据库,美国科学引文索引（扩展库）,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊（2004版）,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）,中国北大核心期刊（2000版）
  • 被引量:14408