研究了在不同影响因素下,人工生物膜对水介质中c。纳米晶体颗粒物的吸附行为.结果表明,nC60能够被人工生物膜吸附,且吸附量受C60纳米晶体颗粒物初始浓度、pH和吸附剂量的影响.吸附等温线可用Henry线性分配模型及Freundlich模型进行数学描述.当溶液中nC60初始浓度由1.0mg·L^-1增大到11.6mg·L^-1时,人工生物膜对c。纳米晶体颗粒物的吸附量由111.9mg·kg^-1增大至813.2mg·kg^-1;随溶液pH值从8(自然中水的pH)到3(生理中相关pH最低限)逐渐减小,nC60在人工生物膜中积累量稳定增长,其吸附量由258.4mg·kg。增大到742.0mg·kg^-1;当c60纳米晶体颗粒物浓度为5.2mg·L^-1时,0.3g人工生物膜的吸附效率最大.
Work presented here evaluated adsorption of aqueous aggregates of C60 fullerene nanoparticles (. nC60 ) on artificial biological membranes under different influencing factors. The results show that the artificial biological membranes can adsorb nC60 and the adsorption capacity of nC60 was impacted by initial nC60 concentrations, pH, and amount of adsorbent. Both Henry linear partition model and Freundlich model were used for data fitting of the sorption isotherms of nC60. The adsorption capacity of nC60 increased with increasing initial nC60 concentration. When the initial nC60 concentration increased from 1.0 mg" L- 1 to 11.6 rag" L- 1, the adsorption capacity of nC60 increased from 111.9 mg'kg-~ to 813.2 mg'kg-1. The adsorption capacity of nC60 were also pH-dependent with the accumulation of nC60 onto artificial biological membranes increasing systematically as the pH decreased from 8 ( natural water pH) to 3 ( the low end of physiologically relevant pH), and its maximum value increased from 258.4 mg. kg^-1 to 742.0 mg. kg^-1. When the initial nC60 concentration was designed at 5.2 mg.L^-1,it was found that artificial biological membranes of 0.3 g had the optimal adsorption for nC60.