不同温度下地层水-烃源岩相互作用模拟实验结果表明:(1)在整个实验温度范围内(60—300℃),均有有机酸的生成,有机酸的总浓度在35.4mg/l至153.9mg/l之间,其中在100℃和140℃的温度下浓度最大,其它温度下浓度相对较低;(2)在低温(60℃)条件下,成熟度相对较高、有机碳含量较大的烃源岩,有利于生成有机酸,但是在中温(140℃)和高温(180℃、220℃和300℃)条件下,有机酸的生成受有机碳含量、成熟度和碳酸盐含量的多重影响;(3)中低温(60℃和140℃)时,随着碳酸盐含量的增加,有机酸浓度表现为逐渐降低的趋势,表明在60-140℃,有机酸对碳酸盐的溶解和沉淀起主要的控制作用,而高温(180℃、220℃和300℃)条件下,碳酸盐的溶解和沉淀作用受有机酸和CO2的共同控制,从而导致有机酸浓度与碳酸盐的关系变化复杂。
The experimental results of formation water-source rock interaction in different temperature suggest the following results:( 1 ) organic acid is generated in the experimental temperatures (60 ~ 300℃ ), the total contents of organic acids is between 35.4 mg/l and 153.9 mg/l. The contents of organic acids are higher in the temperatures of 100℃ and 140℃ than that other temperatures; (2) the source rocks with high maturity (Ro )and high total organic carbon content(TOC) are favorable to the generation of organic acids in the low temperature( 60℃ ), but the generation of organic acids are commonly controlled by the maturity (Ro), total organic carbon content(TOC) and carbonate content of source rocks in the middle( 140℃ ) and high temperature( 180℃ ,220℃ and 300℃ ) ; ( 3 ) the contents of organic acids gradually decrease with the increase of carbonate content in source rocks in the low and middle temperature (60℃ and 140℃ ), it suggests that the dissolution and precipitation of carbonate are mainly controlled by organic acids in the range of 60℃ to 140℃, but the dissolution and precipitation of carbonate are commonly controlled by organic acids and CO2 in the high temperature( 180℃ ,220℃ and 300℃ ), it makes the correlation between organic acids and carbonate complicated.