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Entropy dominated behaviors of confined polymer-nanoparticle composites
  • ISSN号:1674-1056
  • 期刊名称:《中国物理B:英文版》
  • 时间:0
  • 分类:O531.5[理学—等离子体物理;理学—物理] TB332[一般工业技术—材料科学与工程]
  • 作者机构:[1]Department of Physics and ITPA, Xiamen University, Xiamen 361005, China, [2]Leibniz-Institut fur Polymerforschung Dresden, Dresden 01069, Germany
  • 相关基金:Project supported by the National Natural Science Foundation of China (Grant Nos. 10974162 and 11074208).
中文摘要:

Stretched polymers will lose their possible configurations if they are mixed with nanoparticles or touch a hard wall,which leads to a strong depletion attraction responsible for the enrichment of nanoparticles near substrates.Moreover,it is found that there exists a sacrifice mechanism in confined pure polymer samples or polymer-nanoparticle mixtures,that part of the polymers,in order to reach a minimum free energy for the total system,are adsorbed on hard walls even though they lose their conformation.The current study provides a simple yet effective approach for the design of thin polymer composites.

英文摘要:

Stretched polymers will lose their possible configurations if they are mixed with nanoparticles or touch a hard wall, which leads to a strong depletion attraction responsible for the enrichment of nanoparticles near substrates. Moreover, it is found that there exists a sacrifice mechanism in confined pure polymer samples or polymer-nanoparticle mixtures, that part of the polymers, in order to reach a minimum free energy for the total system, are adsorbed on hard walls even though they lose their conformation. The current study provides a simple yet effective approach for the design of thin polymer composites.

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期刊信息
  • 《中国物理B:英文版》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国物理学会和中国科学院物理研究所
  • 主编:欧阳钟灿
  • 地址:北京 中关村 中国科学院物理研究所内
  • 邮编:100080
  • 邮箱:
  • 电话:010-82649026 82649519
  • 国际标准刊号:ISSN:1674-1056
  • 国内统一刊号:ISSN:11-5639/O4
  • 邮发代号:
  • 获奖情况:
  • 国内外数据库收录:
  • 被引量:406