采用流变学方法研究了具有高PEO质量分数(80%)的两亲性三嵌段共聚物Pluronic F68(PEO80-PPO30-PEO80)和F108(PEO133-PPO50-PEO133)的水溶液在升温过程中的溶胶-凝胶转变过程,发现对于特定浓度的嵌段共聚物水溶液,在溶胶-凝胶转变过程中会出现一个"软凝胶"区域,通过对F68进行区域的频率扫描实验,推测了相应的内部结构.
Using the rheology method,the sol-gel transitions of amphiphilic triblock copolymers Pluronic F68(PEO80-PPO30-PEO80) and F108(PEO133-PPO50-PEO133) were studied with increasing the temperature.The "soft gel" regions were found during the sol-gel transition process for the aqueous solutions with some concentrations.It is inferred that the structure of the "soft gel" region by the frequency scanning experiment for F68 aqueous solution.