摘要针对制革废水高COD、高总氮的问题,提出了基于上流式厌氧污泥床(UASB)、上流式反硝化污泥床(UDNSB)、生物接触氧化池的生物处理组合工艺,进行了为期321d的现场中试研究。研究结果表明,对于COD、TN、NH4+-N平均浓度分别为2740、278和193mg·L-1的制革废水,在硝化液回流比R为300%,UASB反应器、UDNSB反应器、生物接触氧化池的水力停留时间(HRT)分别为11、22和57h,平均容积负荷分别为5.63kgCOD·(m3·d)-1、0.30kgTN·(m3·d)-1和0.11kgNH4+-N·(m3·d)-1的条件下,该组合工艺处理出水COD、TN和NH4+-N的平均浓度分别为190、69.8和4.6mg·L-1,其平均去除率分别达到92%、73%和97%以上。
Tannery wastewater is characterized by high concentrations of chemical oxygen demand (COD) and total nitrogen (TN). In this study, a combined biological treatment process based on an up-flow anaerobic sludge blanket (UASB), an up-flow denitrification sludge blanket (UDNSB), and a biological contact oxidation pond was proposed to treat tannery wastewater. A pilot wastewater treatment system was operated for 321 days, with ef- ficient removal rates of COD, TN, and NH4+ -N. The hydraulic retention times (HRTs) of the UASB, UDNSB, and biological contact oxidation pond were 11, 22, and 57 h, respectively, and the corresponding volumetric loadings were 5.63 kg COD · (m3 · d) -1, 0. 30 kg TN · (m3 · d) -1, and 0. 11 kg NH4+-N - (m3 · d) -1, with a nitrification liquid reflux ratio (R) of 300%. Average concentrations of COD, TN, and NH4+ -N in the tan- nery wastewater were 2 740, 278, and 193 mg · L-1, respectively. After the combined biological treatment, the average concentrations of COD, TN, and NH4 +-N in the final effluent were 190, 69.8, and 4.6 mg · L-1, with removal rates of more than 92% , 73% , and 97% , respectively.