以工业戊烷为原料,在萃取温度15 ℃、静置时间15 min、剂油比为1:1的条件下,考察了多种萃取剂的萃取脱硫性能。实验结果表明,糠醛和NaOH溶液作为单一萃取剂的效果较好,可将工业戊烷中的硫由原来的40.3 mg/L降低到1mg/L; 5%NaOH溶液与95%乙醇在较宽的体积比范围内进行复配可将戊烷中硫含量降低到1mg/L; 当N,N-二甲基甲酰胺与5%NaOH溶液按照体积比为1:1进行复配时,可将戊烷中的硫含量降低到1 mg/L,但N,N-二甲基甲酰胺含量过高则会抑制复合萃取剂的脱硫效果。
The desulfurization performance of several extraction agents were studied using industrial pentane as feed under the conditions of an extraction temperature of 15℃, a settling time of 15 min and an agent to oil ratio of 1. Test results indicated that: (1) As to single extraction agent, furfural and NaOH solution are preferred, which can reduce the sulfur content of pentane from 40.3 mg/L to 1.0 mg/L; (2) 5%NaOH solution and 95% ethanol could be formed composite agent in rather wide volume ratios, which can reduce the sulfur content of pentane to 1.0 mg/L; (3) Composite agent of DMF and 5%NaOH mixing with a volume ratio of 1 can reduce the sulfur content of pentane to 1.0 mg/L, yet exceeded amount of DMF in composite agent might suppress the removal of sulfides from pentane.