欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
中文摘要：
通过等体积浸渍法制备了金属有机骨架材料MIL-53（AI）（MIL：MaterialsofInstitutLavoisier）负载纳米Pd催化剂．采用X射线衍射（XRD）、透射电子显微镜（TEM）和X射线光电子能谱（XPS）等手段对催化剂的结构进行了表征．催化剂在反应前后XRD衍射峰保持不变，说明载体MIL一53（AI）具有良好的稳定性．采用TEM对催化剂进行表征，结果表明，MIL．53（AI）的多孔晶体结构有助于形成高度分散的纳米Pd颗粒，样品2.7％（w）Pd／MIL．53中Pd颗粒的平均粒径为2．21nm．该催化剂在CO氧化反应中表现出较高的催化活性，115℃达到完全转化．同时催化剂可循环使用，多次反应后催化活性和催化剂结构都保持稳定．
英文摘要：
Pd nanoparticles （NPs） supported on a metal-organic framework （MOF）, MIL-53（AI） （MIL： Ma- terials of Institut Lavoisier）, were prepared using the incipient wetness impregnation method. The struc- tures of the synthesized Pd/MIL-53（AI） catalysts were determined using X-ray diffraction （XRD）, transmis- sion electron microscopy （TEM）, and X-ray photoelectron spectroscopy （XPS）. The same peaks were ob- served in the XRD patterns of Pd/MIL-53（AI） before and after the catalytic reaction, confirming that the in- tegrity of the MIL-53（AI） support was maintained. The TEM results indicated that the crystalline porous structure of MIL-53（AI） favored the formation of highly dispersed Pd NPs of average size 2.21 nm. The het- erogeneous catalytic composite materials exhibited high activities for CO oxidation, with full conversion at 115 ℃. The catalytic activity and structure of Pd/MIL-53（AI） were stable after several reaction runs.
同期刊论文项目
同项目期刊论文
Synthesis of AuPt alloy nanoparticles supported on 3D ordered macroporous oxide with enhanced cataly
One-pot synthesis of core-shell Au@CeO2-delta nanoparticles supported on three-dimensionally ordered
Periodic DFT study on mechanism of selective catalytic reduction of NO via NH3 and O-2 over the V2O5
Three-dimensionally ordered macroporous SiO2-supported transition metal oxide catalysts: facile synt
Photocatalysts of 3D Ordered Macroporous TiO2-Supported CeO2Nanolayers: Design, Preparation, and The
Selective catalytic reduction of NO with NH3 over HZSM-5-supported Fe-Cu nanocomposite catalysts: th
Therr- dimensionally Ordered Macroporous MnxCe1-xOδ and Pt/Mn0.5Ce0.5Oδ Catalysts: Synthesis and Cat
Synthesis of three-dimensionally ordered macroporous Al–Ce mixed oxide catalysts with high catalytic
Facile synthesis of three-dimensionally ordered macroporous LaFeO3-supported gold nanoparticle catal
Preparation of ultrafine Ce-based oxide nanoparticles and their catalytic performances for diesel so
Three-Dimensionally Ordered Macroporous MnxCe1-xO delta and Pt/Mn0.5Ce0.5O delta Catalysts: Synthesi
Multifunctional catalysts of three-dimensionally ordered macroporous oxide-supported Au@Pt core-shel
Preparation, characterization and origin of highly active and thermal stable Pd-Ce0.8Zr0.2O2 catalys
Synthesis of K-doped three-dimensionally ordered macroporous Mn0.5Ce0.5O delta catalysts and their c
The catalysts of three-dimensionally ordered macroporous Ce1-xZrxO2-supported gold nanoparticles for
Comparative Study of Nanometric Co-, Mn- and Fe-based Perovskite-type Complex Oxide Catalysts for th
One-Pot Synthesis of Core-Shell Au@CeO2-δ Nanoparticles Supported on Three-Dimensionally Ordered Mar
Three-dimensionally ordered macroporous CeZrO2-supported Pt nanoparticles catalysts with super perfo
Dehydrogenationof propane over PtSnAlSBA-15 catalysts: Al addition effect and coke formation analysi
Structural and synergistic effects of three-dimensionally ordered macroporous Ce0.8Zr0.2O2-supported
Potassium-modified molybdenum-containing SBA-15 catalysts for highly efficient production of acetald
Selective Oxidation of Ethane to Aldehydes over Potassium-Promoted SBA-15-Supported Molybdenum Oxide
Preparation, characterization and origin of highly active and thermally stable Pd-Ce0.8Zr0.2O2 catal
Pd Nanoparticles Deposited on Metal-Organic Framework of MIL-53(Al): an Active Catalyst for CO Oxida
Potassium modified molybdenum-containing SBA-15 catalysts for highly efficient producing acetaldehyd
Dehydrogenationof propane over PtSn/SBA-15 catalysts: effect of the amount of metal loadingand state
Synthesis of AuPt alloynanoparticles supported on 3D ordered macroporous oxide with enhanced catalyt
The novel catalysts of truncated polyhedron Pt nanoparticles supported on three-dimensionally ordere
Highactivity and wide temperature window of Fe-Cu-SSZ-13 in the selective catalyticreduction of NO w
Synthesis of a new ordered mesoporous NiMoO4 complex oxide and its efficient catalytic performance f
The structure and activity of potassium supported on SBA-15 molecular sieve: Density Functional Theo
Easy synthesis of three-dimensionally ordered macroporous La(1-x)K(x)CoO(3) catalysts and their high
Optimal synthesis of micro/mesoporous beta zeolite from kaolin clay and catalytic performance for hy
期刊信息
位置：