在水溶液中合成铕与5-氨基间苯二甲酸的配合物。该配合物在紫外灯下发出明亮的红光,紫外-可见吸收光谱表明配合物的紫外吸收主要是配体的吸收;红外光谱的结果表明配合物中Eu3+与羰基氧双齿螯合配位;荧光光谱研究表明配合物具有良好的荧光性能,最佳激发波长为395 nm,发射光谱为Eu3+ 的特征光谱,发光强度最高的是波长为616 nm的5D0 → 7F2跃迁,峰形尖锐,半峰宽仅7 nm,Eu3+ 处于无反演对称中心格位上,荧光发光机制属于M-M型
Complex of europium with 5-aminoisophthalic acid was synthesized in the aqueous solution. The complex has bright red light when excited by UV light. UV-Vis absorption spectra of the complex show that the UV absorption is mainly from the ligand. FTIR spectra indicate that in the complex Eu3+ was coordinated with carbonyl oxygen in the form of bidentate chelate. And excellent fluorescence property is confirmed by the fluorescence spectrum. Optimal excitation wavelength is 395 nm, and the emission spectrum is the characteristic spectrum of Eu3+; there is a sharp and strong red peak with 7 nm mid-width at 616 nm, which is attributed to 5D0→7F2 transition from Eu3+ ions; Eu3+ exists in the site without inversion symmetrical center. Meanwhile, the fluorescence spectrum of the complex reveals the M-M fluorescence mechanism