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寿光土壤中多环芳烃的污染特征及风险评估
  • ISSN号:1000-6923
  • 期刊名称:《中国环境科学》
  • 时间:0
  • 分类:X142[环境科学与工程—环境科学]
  • 作者机构:[1]中国科学院广州地球化学研究所有机地球化学国家重点实验室,广东广州510640, [2]中国科学院大学,北京100049
  • 相关基金:基金项目:国家自然科学基金项目(41230639);广东省自然科学基金资助项目(S2011010006081)
中文摘要:

以山东省寿光市为研究区域,采集了39个土壤样品,分析了26种PAHs的含量.结果表明,26种多环芳烃的浓度范围为120-1486μg/kg,平均值为(415±312)μg/kg.16种优控PAHs的浓度范围为84-1076μg/kg,平均值为(289±211)μg/kg.与我国其他区域非点源污染土壤相比,寿光市土壤中PAHs含量处于中等水平.采用克里格(Kriging)插值方法对寿光市土壤中PAHs的空间分布特征进行预测发现。该市PAHs高污染区位于东部开发区和西部工业园,高环与低环PAHs在空间分布上有明显差异.主成分分析结果显示,该市土壤中PAHs有3个主要来源,分别为液体化石燃料燃烧源、石油源以及煤燃烧源,其对主要来源的贡献率分别为44.7%、31.7%和23.6%.相关性分析表明,低环和高环PAHs与土壤有机质含量均显著相关,但低环PAHs的相关系数明显高于高环PAHs,表明低环PAHs更容易受到土壤中有机质的影响,而高环PAHs则受控于近距离沉降.对照荷兰的土壤管理标准,寿光市土壤中Flt和Phe超标较严重,TEQBaP以及致癌风险计算结果表明,寿光市土壤PAHs处于较低风险水平.

英文摘要:

Polycyclic aromatic hydrocarbons (PAHs) were analyzed in 39farmland soil samples collected from Shouguang City. The concentrations ranged from 120 to 1486 μg/kg [averaged (415 ± 312)μg/kg] for the 26 PAHs and from 84 to 1076 μg/kg [averaged (289 ± 211) μg/kg] for the 16PAHs. The PAH levels in Shouguang farmland soils were generally moderate compared to those in soils with non-point sources in China. Kriging interpolation map showed two highly contaminated areas that were located in the two industrialized areas in the eastern and western parts, respectively. Moreover, high-molecule weight and low-molecule weight PAHs (HWPAHs and LWPAHs) showed distinct spatial distributions in the soil. Principal components analysis indicated that combustion of fossil fuel, petroleum, and coals burning were the three primary sources of PAHs in soils of Shouguang City, with contributions of 44.7%, 31.7% and 23.6%, respectively. HWPAHs and LWPAHs were both correlated significantly with soil organic matter (SOM), but the correlation was more significant for LWPAHs. This suggested that LWPAHs were more susceptible to SOM than HWPAHs, which were easily controlled by local deposition. Fit and Phe in most soil exceeded the soil quality guidelines of Netherland. The incremental lifetime cancer risk associated with the PAHs in the soils in this region was basically low.

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期刊信息
  • 《中国环境科学》
  • 中国科技核心期刊
  • 主管单位:中国科协
  • 主办单位:中国环境科学学会
  • 主编:王文兴
  • 地址:北京市海淀区红联南村54号
  • 邮编:100082
  • 邮箱:zghjkx1981@126.com
  • 电话:010-62215145
  • 国际标准刊号:ISSN:1000-6923
  • 国内统一刊号:ISSN:11-2201/X
  • 邮发代号:2-572
  • 获奖情况:
  • 国家期刊提名奖,国家“双效”期刊,第三届中国科协优秀科技期刊一等奖
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),英国农业与生物科学研究中心文摘,波兰哥白尼索引,荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,英国科学文摘数据库,英国动物学记录,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:47702