中文摘要：

利用高温烧结法制备了铕/铋铕共掺硼硅酸盐玻璃系列样品，测量了样品的激发光谱、发射光谱和声子边带谱，利用Eu^3＋离子作为探针进一步研究了敏化剂Bi^3＋的掺入对Eu^3＋发光的影响.结果表明：本文制作的玻璃样品的电子-声子耦合系数比以往报道过的硼铅等玻璃材料的值都要小，但在硼硅酸盐玻璃中掺入Bi^3＋会使Eu^3＋的无辐射跃迁概率增加；Bi^3＋对Eu^3＋有敏化作用，Bi^3＋的掺入使材料的共价性增强，对称性降低，这又使得Eu^3＋的发光整体变强.所以，在硼硅酸盐玻璃体系中，Eu^3＋发光的增强不仅仅是由于Bi^3＋对Eu^3＋的能量传递，而是以上各因素综合作用的结果.

英文摘要：

A series of samples about Eu^3＋ doped, Bi^3＋∶Eu^3＋-codoped borosilicate glasses have been prepared by high-temperature sintering. The excitation spectra, emission spectra and the phonon sideband spectra of the samples were measured. The influence on the luminescence of Eu^3＋ ions was discussed with Eu^3＋ ions as probe when Bi^3＋ions were doped. The results show that the electron-phonon coupling coefficient calculated in this study is smaller than those of borate-lead glasses and others reported before, but the probability of non-radiative transition of Eu^3＋ ions is increased by the doping of Bi^3＋ ions. The Bi^3＋ ions can sensitize Eu^3＋ ions, and when Bi^3＋ ions are doped, the covalent property becomes bigger with the symmetry becoming smaller ,which enhances the luminescence intensity of Eu^3＋ ions on the whole. Therefore, in the borosilicate glasses, the increase of luminescence intensity about Eu^3＋ ions is the result of the combined action between the above factors,not simply because of the energy transition from Bi^3＋ ions to Eu^3＋ ions.