采用湿化学法合成系列阴极材料Ba1-xPrxCoO3(x=0.3,0.4,0.5,0.6).TG—DTA和烧结曲线测试结果表明,在950℃时样品发生相变,形成了晶相.样品的SEM结果显示,Pr离子掺杂到一定量时,将抑制品粒长大,减少阴极的孔洞率.单电池测量结果表明,用x=0.5的阴极材料制成的单电池表现出最好的输出特性,具有最大短路电流密度和最大输出功率密度,是掺杂Y的BaCeO3基电解质的一种优化配比阴极材料.
Cathode materials Ba1-x PrxCoO3 (x = 0.3, 0.4, 0. 5, 0. 6) were prepared with wet chemical method. TG-DTA and sintering curves show that the materials were crystallized in a single perovskite phase at around 950 ℃. The SEM images show that the prohibition of the particle growth and the decrease of the hole ratio were produced when the increase of Pr ions dopant to a certain quantity. The results of the single cell tests show that the fuel cell with the cathodes x = 0. 5 have the best output performance and the greatest short current density and the maximum output power density, so it has more proper ratio than the other samples and fit Y^3+ -doped BaCeO3 based solid electrolyte material perfectly.