以3种介孔碳CMK-3、立方Ia3d结构介孔碳和层状介孔碳MMC为吸附剂,考察了它们对亚甲基蓝的吸附效果;利用Langmuir和Freundlich吸附等温模型来描述3种介孔碳对亚甲基蓝的吸附行为,Langmuir等温模型的拟合性更好;利用准1级和准2级动力学模型考察吸附动力学,3种介孔碳吸附亚甲基蓝的动力学曲线更符合准2级动力学模型,吸附速率常数分别为0.007 3、0.002 0、0.004 8 g/(mg·min),且均是单分子层的物理作用;3种介孔碳中CMK-3对亚甲基蓝的吸附量最高,为3.067 g/g。
Three kinds of mesoporous carbon including CMK-3, Cubic Ia3d mesoporous carbon and lamellar mesoporous carbon MMC were used as adsorbents, and the removal efficiency of methylene blue (MB) from aqueous solution by them was investigated. The adsorption parameters for Langmuir and Freundlich isotherm models were determinod for these mesoporous carbons. Both isotherms were suitable models to analyze the equilibrium data for the methylene blue adsorption. However, the Langmuir model fitted better than the Freundlich model. The adsorption kinetics was tested with pseudo- first-order and pseudo-second-order reaction model. The pseudo-second-order kinetic, model provided better correlation of the experimental data compared with the pseudo-first-order modal. The adsorption rate constants were 0.007 3, 0.002 0 and 0.004 8 g/(mg·min), respectively. MorevoVer, physical interaction was the removal mechanism of all these kinds of mesoporous carbon for methylene blue. The results indicated that CMK-3 had the highest adsorption capacity among the three kinds ofmesoporous carbon, and adsorption capacity reached 3.067 g/g.