以高温凝结水的净化为应用背景,采用孔径为4nm的陶瓷膜去除水中微量Fe3+。考察Fe^3+浓度、pH及操作参数等对陶瓷膜分离性能的影响。结果表明:随着Fe3+浓度增大,陶瓷膜对Fe^3+的去除率减小;当Fe^3+质量浓度小于50mg/L时,陶瓷膜对Fe^3+的去除率大于98%,操作条件如温度和膜面流速(CFV)的提高均有利于提高陶瓷膜对Fe^3+的截留率;温度升高有利于提高膜过滤通量,操作压力对通量的拐点为0.2MPa,膜面流速的拐点在3m/s左右;pH对Fe3+的去除率影响显著,主要由于pH影响了Fe3+在水中的化学构成。
The purification of high-temperature condensed water was necessary. Removal of Fe3+ with ce- ramic membrane of nominal pore size 4 nm from water solution was studied. The effects of Fe3 + concentra- tion, pH and operation parameters on the separation performances of ceramic membrane were investigated. The Fe3+ rejection rate decreased with the increasing of Fe3+ concentration. The Fe3+ rejection rate with ceramic membrane was more than 98% when Fe3+ concentration was less than 50 mg/L. The rejection rate was improved with the increasing of the temperature and cross-flow velocity (CFV). The permeate flux increased with the increasing of the temperature, and leveled off at operation pressure 0.2 MPa. Mean- while, the permeate flux also increased with CFV when CFV about 3 m/s. pH had a major influence on the rejection rate, and it affected by the chemical forms of Fe3+ in solution.