用四氢呋喃(THF)络合还原法制备了直接甲醇燃料电池(DMFC)阴极用Ir-Ru/C催化剂,研究了n(Ir):n(Ru)对Ir-Ru/C催化剂对氧还原的电催化活性和抗甲醇能力的影响。当n(Ir):n(Ru)=3:1时,Ir-Ru/C催化剂具有很好的抗甲醇能力,对氧还原的电催化活性好于n(Ir):n(Ru)=1:1和2:1时,也好于Ir/C催化剂和Ru/C催化剂。
Ir-Ru/C catalyst for the cathode of direct methanol fuel cell (DMFC) was prepared by tetrahydrofuran (THF) complexing reduction method. The effects of n(Ir) : n(Ru) to electrocatalytic activity for the oxygen reduction and the methanol tolerance ability of Ir-Ru/C catalysts were studied. The Ir-Ru/C catalyst with n (Ir) : n (Ru) = 3 : 1 had fine methanol tolerance ability, its electrocatalytic activity for the oxygen reduction was better than that of which n (Ir) : n (Ru) = 1 : 1 and 2 : 1,it was also better than that of Ir/C catalyst and Ru/C catalyst.