The First Total Synthesis of Phebaclavin A and C
- ISSN号:1001-604X
- 期刊名称:《中国化学:英文版》
- 时间:0
- 分类:O629[理学—有机化学;理学—化学]
- 作者机构:[1]State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, Gansu 730000, China
- 相关基金:Project supported by the National Natural Science Foundation of China (No. 20472025) and QT Program (No. 20021001).
中文摘要:
Phebaclavin A (1 ) 和 C (2 ) 在超过 5 分别地从商业地可得到的开始的 meterials 走的 60% 和 58% 全部的收益被综合。合成特征是 Wittig 反应的用法两次,没有溶剂的 cyclizing 反应作为钥匙走。
英文摘要:
Phebaclavin A (1) and C (2) were synthesized in 60% and 58% total yields over 5 steps from commercially available starting meterials respectively. The synthesis feature was usage of the Wittig reaction twice and solvent-free cyclizing reaction as the key steps.