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Synthesis, Photochromic Kinetics, Fluorescence and Structure of a New 1,2-Diarylcyclopentene
  • ISSN号:1001-604X
  • 期刊名称:《中国化学:英文版》
  • 时间:0
  • 分类:O624.12[理学—有机化学;理学—化学]
  • 作者机构:[1]Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013, China
  • 相关基金:Project supported by the National Natural Science Foundation of China (No. 20564001), the Natural Science Foundation of Jiangxi Province (No. 050017) and the Science Funds of the Education Commission of Jiangxi Province (No. [2005] 140).
中文摘要:

对光反应变色 diarylethene, 1,2 二度[2-methyl-5-(3-trifluoromethylphenyl )-3-thienyl]perfluorocyclopentene (BMTTP ) ,被综合,它的对光反应变色动力学,荧光和 X 光检查结构被调查。这混合物在溶液和单个水晶的阶段两个都经历了对光反应变色反应。它的 cyclization/cycloreversion 过程决心分别地,是 zeroth/first 顺序反应,这是 cyclization/cycloreversion 反应顺序上的第一份报告。另外,它的荧光性质也被讨论。

英文摘要:

The photochromic diarylethene, 1,2-bis[2-methyl-5-(3-trifluoromethylphenyl)-3-thienyl]perfluorocyclopentene (BMTTP), was synthesized and its photochromic kinetics, fluorescence and X-ray structure were investigated. This compound underwent a photochromic reaction both in solution and the single crystalline phase. Its cyclization/cycloreversion process was determined to be zeroth/first order reaction, respectively, and this is the first report on the cyclization/cycloreversion reaction order. In addition, its fluorescence property was also discussed.

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期刊信息
  • 《中国化学:英文版》
  • 主管单位:
  • 主办单位:中国化学会
  • 主编:
  • 地址:上海市枫林路354号中科院上海有机化学研究所
  • 邮编:200032
  • 邮箱:
  • 电话:021-54925243
  • 国际标准刊号:ISSN:1001-604X
  • 国内统一刊号:ISSN:31-1547/O6
  • 邮发代号:4-646
  • 获奖情况:
  • 中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,英国英国皇家化学学会文摘
  • 被引量:175