中文摘要：

在无溶剂条件下研究了稀土胺基化合物[（Me3Si）2N]3Y（μ-Cl）Li（THF）3催化环己酮与对甲基苯磺酰亚胺的Mannich加成反应.此反应具有原料不需活化,催化剂经济易得,反应条件温和,反应污染小等特点.

英文摘要：

Lanthanide amide [（Me3Si）2N]3Y（μ-Cl）Li（THF）3 was found to be a good catalyst for the Mannich reaction of N-Tosylaldimines with cyclohexanone under solvent-free condition.Compared with the traditional reactions,the reactant of cyclohexanone can be directly put into the reaction without through the silyl enol ether.The methodology has the advantages of economical catalyst,broad generality,mild and green reaction condition.