研究了BP/THF引发体系引发降冰片烯(NB)与马来酸酐(MA)自由基光聚合性能。考察了单体和引发剂浓度、第三单体的加入和氛围对共聚合收率的影响。采用红外光谱(FTIR)、核磁共振谱(NMR)、元素分析和高效凝胶液相色谱(GPC)对聚合物进行了表征与分析。在单体比为1∶1时,共聚物中NB和MA的含量分别为54.2%和47.8%。
The characteristics of the visible radical photopolymerization of norbornene(NB) with maleic anhydride(MA) initiated by benzophenone/THF were studied.The effects of monomer concentration,atmosphere,initiator concentration and the third comonomer on the yield of copolymerization were investigated.The copolymer structure was characterized by IR,NMR,GPC and elemental analysis.The copolymer was a product of high alternation,and the content of NB and MA were 54.0% and 46.0% respectively,when n(MA)/n(NBE)=1.