设计合成了C60键联1,4-二-(咔唑-9-亚甲基)苯(5)和C70键联1,4-二-(咔唑-9-亚甲基)苯(6),用红外、核磁共振和MALDI—TOF质谱进行了表征,确认了化合物5和6的结构,用循环伏安法研究了化合物5和6的电化学性质,并用Z扫描对其双光子吸收性质进行了研究.
C60/C70 bonded with 1,4-bis [ (carbazole-9-yl)methyl ] benzene was synthesized and characterized by FTIR, ^1H NMR and MALDI-TOF. Electrochemical properties of compounds 5 and 6 were studied by cyclic vohammetry. In the meanwhile, two-photon absorption cross-sector values ( σTPA) of derivatives were also tested by open aperture Z scan experiment.