中文摘要：

在铜离子诱导效应下，采用水热方法，以Or-Keggin型磷钼酸和1，6-己二胺为原料首次成功合成了四电子还原态仪．Keggin型磷钼酸基有机／无机杂化超分子化合物，并利用X射线单晶结构解析、元素分析、IR、UV-Vis、TG／DTA、XPS、磁化率测量以及CV等方法对标题化合物进行了详尽的结构和光谱研究．

英文摘要：

The first four-electron reduced α-Keggin type phosphomolybdate-based organic-inorganic hybrid supramolecule compound was hydrothermally synthesized in the necessary presence of copper ion by reacting α- Keggin type phosphomolybdic acid and 1,6-hexanediamine, and characterized thoroughly via single-crystal X- ray diffraction, elemental analysis, IR,UV-Vis, TG/DTA, XPS, magnetic and electrochemical studies.