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新疆阿尔泰可可托海3号伟晶岩脉岩浆-热液过程:来自电气石化学组成演化的证据
  • ISSN号:1000-4734
  • 期刊名称:《矿物学报》
  • 时间:0
  • 分类:P581[天文地球—岩石学;天文地球—地质学]
  • 作者机构:[1]贵州省有色金属和核工业地质勘查局七总队,贵州贵阳550005, [2]中国科学院地球化学研究所地球内部物质高温高压院重点实验室,贵州贵阳550081, [3]中国科学院大学,北京100049
  • 相关基金:国家自然科学基金项目(批准号:41372104); 新疆有色金属工业(集团)有限责任公司科研项目(批准号:2011YSKY-02)
中文摘要:

新疆阿尔泰可可托海3号脉不同结构带及其蚀变围岩中电气石化学组成电子探针(EMPA)分析结果显示,蚀变围岩、外接触带和内接触带中电气石为是富钙-铁的镁电气石,电气石化伟晶岩中电气石为富镁-铁的锂电气石,伟晶岩早期结构带(Ⅰ-Ⅳ带)中电气石为黑电气石-锂电气石系列,而伟晶岩晚期结构带(Ⅴ-Ⅶ带)中电气石为锂电气石。蚀变围岩、外接触带和内接触带中电气石以Y位中低Al,高Mg、Ca以及显著低的Al/(Al+Fe)、Fe/(Fe+Mg)比值为特征,主要存在R3++O2-=R2++OH-的置换;伟晶岩内部结构带(Ⅰ-Ⅶ带)中电气石以Y位上极低Mg、Ca,高Fe、Al、Li以及显著高的Al/(Al+Fe)、Fe/(Fe+Mg)比值为特征,主要存在+Al3+=Na++Fe(Mg)2+和Li++Al3+=Fe(Mn)2++Mg2+的置换。蚀变围岩、外接触带和内接触带中电气石化学组成特征指示存在围岩-流体、围岩-熔体相之间的相互作用。伟晶岩早期结构带(Ⅰ-Ⅳ带)中电气石无明显组成分带,为岩浆成因;晚期结构带(Ⅴ-Ⅶ带)中电气石显示振荡环带,形成于岩浆-热液过渡阶段体系。随着伟晶岩由外向里固结,温度逐渐降低,伟晶岩内部结构带中电气石显示Y位上Al、Li、Mn及Fe/(Fe+Mg)比值逐渐增大的演化趋势;内部结构带中电气石几乎不含Mg,指示3号伟晶岩脉岩浆-热液演化是在相对封闭体系中进行的。

英文摘要:

Chemical compositions of tourmalines, determined by electron microprobe, show that tourmalines from the altered country-rock, exo- and internal-contact zones are Ca- and Fe-rich dravite, from the tourmalized pegmatite are Mg- and Fe-rich elbaite, from the early formed textural zones(Ⅰ-Ⅳ) are schorl-elbaite solid solution series, and from the late formed textural zones(Ⅴ-Ⅶ) are elbaite. Tourmalines from the altered country-rock, exo- and internal- contact zones are characterized by low Al, high Mg and Ca in Y site, and very low ratios of Al/(Al+Fe) and Fe/(Fe+Mg), represented by substitution of R3++O2-=R2++OH-, indicating that the origin of tourmalines were associated with interactions between country-rock and exsolved magmatic fluid, and/or between country-rock and pegmatite-forming melt. Tourmalines from the internal textural zones(Ⅰ-Ⅶ) of pegmatite are featured by very low Mg and Ca, high Fe, Al and Li in Y site, and very high ratios of Al/(Al+Fe) and Fe/(Fe+Mg), represented by substitution of +Al3+=Na++Fe(Mg)2+ and Li++Al3+=Fe(Mn)2++Mg2+, respectively. Touramlines from the early formed textural zones(Ⅰ-Ⅳ) of pegmatite are magmatic in origin, showing no zonation in chemical compositions, but tourmalines from the late formed textural zones(Ⅴ-Ⅶ) of pegmatite were magmatic-hydrothermal in origin, featured by oscillatory zonation. As solidification of pegmatite from the outer to the inner, it shows that Al, Li and Mn in Y site and Fe/(Fe+Mg) ratio of tourmalines increase with decreasing temperature gradually. As no Mg in Y site of tourmalines from the internal textural zones, it indicates that the magmatic-hydrothermal evolution of Koktokay No.3 pegmatite proceeded in a relatively closed system.

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期刊信息
  • 《矿物学报》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国科学院地球化学研究所 中国矿物岩石地球化学学会
  • 主编:胡瑞忠
  • 地址:贵州省贵阳市观山湖区林城西路99号
  • 邮编:550081
  • 邮箱:kwxb@ms.gyig.ac.cn
  • 电话:0851-5891352
  • 国际标准刊号:ISSN:1000-4734
  • 国内统一刊号:ISSN:52-1045/P
  • 邮发代号:66-17
  • 获奖情况:
  • 国内外数据库收录:
  • 被引量:10998