新疆阿尔泰可可托海3号脉不同结构带及其蚀变围岩中电气石化学组成电子探针(EMPA)分析结果显示,蚀变围岩、外接触带和内接触带中电气石为是富钙-铁的镁电气石,电气石化伟晶岩中电气石为富镁-铁的锂电气石,伟晶岩早期结构带(Ⅰ-Ⅳ带)中电气石为黑电气石-锂电气石系列,而伟晶岩晚期结构带(Ⅴ-Ⅶ带)中电气石为锂电气石。蚀变围岩、外接触带和内接触带中电气石以Y位中低Al,高Mg、Ca以及显著低的Al/(Al+Fe)、Fe/(Fe+Mg)比值为特征,主要存在R3++O2-=R2++OH-的置换;伟晶岩内部结构带(Ⅰ-Ⅶ带)中电气石以Y位上极低Mg、Ca,高Fe、Al、Li以及显著高的Al/(Al+Fe)、Fe/(Fe+Mg)比值为特征,主要存在+Al3+=Na++Fe(Mg)2+和Li++Al3+=Fe(Mn)2++Mg2+的置换。蚀变围岩、外接触带和内接触带中电气石化学组成特征指示存在围岩-流体、围岩-熔体相之间的相互作用。伟晶岩早期结构带(Ⅰ-Ⅳ带)中电气石无明显组成分带,为岩浆成因;晚期结构带(Ⅴ-Ⅶ带)中电气石显示振荡环带,形成于岩浆-热液过渡阶段体系。随着伟晶岩由外向里固结,温度逐渐降低,伟晶岩内部结构带中电气石显示Y位上Al、Li、Mn及Fe/(Fe+Mg)比值逐渐增大的演化趋势;内部结构带中电气石几乎不含Mg,指示3号伟晶岩脉岩浆-热液演化是在相对封闭体系中进行的。
Chemical compositions of tourmalines, determined by electron microprobe, show that tourmalines from the altered country-rock, exo- and internal-contact zones are Ca- and Fe-rich dravite, from the tourmalized pegmatite are Mg- and Fe-rich elbaite, from the early formed textural zones(Ⅰ-Ⅳ) are schorl-elbaite solid solution series, and from the late formed textural zones(Ⅴ-Ⅶ) are elbaite. Tourmalines from the altered country-rock, exo- and internal- contact zones are characterized by low Al, high Mg and Ca in Y site, and very low ratios of Al/(Al+Fe) and Fe/(Fe+Mg), represented by substitution of R3++O2-=R2++OH-, indicating that the origin of tourmalines were associated with interactions between country-rock and exsolved magmatic fluid, and/or between country-rock and pegmatite-forming melt. Tourmalines from the internal textural zones(Ⅰ-Ⅶ) of pegmatite are featured by very low Mg and Ca, high Fe, Al and Li in Y site, and very high ratios of Al/(Al+Fe) and Fe/(Fe+Mg), represented by substitution of +Al3+=Na++Fe(Mg)2+ and Li++Al3+=Fe(Mn)2++Mg2+, respectively. Touramlines from the early formed textural zones(Ⅰ-Ⅳ) of pegmatite are magmatic in origin, showing no zonation in chemical compositions, but tourmalines from the late formed textural zones(Ⅴ-Ⅶ) of pegmatite were magmatic-hydrothermal in origin, featured by oscillatory zonation. As solidification of pegmatite from the outer to the inner, it shows that Al, Li and Mn in Y site and Fe/(Fe+Mg) ratio of tourmalines increase with decreasing temperature gradually. As no Mg in Y site of tourmalines from the internal textural zones, it indicates that the magmatic-hydrothermal evolution of Koktokay No.3 pegmatite proceeded in a relatively closed system.