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固体磺酸促进亚硝酸异戊酯催化氧化苯甲醇反应
  • ISSN号：0253-9837
  • 期刊名称：《催化学报》
  • 时间：0
  • 分类：O643[理学—物理化学;理学—化学]
  • 作者机构：[1]中国科学院大连化学物理研究所洁净能源国家实验室,催化基础国家重点实验室,辽宁大连116023, [2]中国科学院研究生院,北京100049
  • 相关基金：国家自然科学基金（20803074,21103206）
作者： 盛学斌[1,2], 马红[1], 李德财[1], 何静[3], 徐杰[1]
关键词： 选择氧化, 分子氧, 甲苯, 4-N, N-二甲胺基吡啶, 溴苄, selective oxidation, molecular oxygen, toluene, 4-N, N-dimethylamino pyridine, benzyl bromide
中文摘要：

以乙酸钴和溴苄为催化剂,考察了三乙胺、2,6-二甲基吡啶、吡啶、4-羧基吡啶和4-N,N-二甲氨基吡啶等不同含氮有机化合物对甲苯氧化反应的影响.结果发现4-N,N-二甲氨基吡啶表现出促进效应,并探讨了其促进机制.

英文摘要：

The influence of different nitrous organic compounds, including triethylamine, 2,6-dimethylpyridine, 4-carboxylic pyridine, pyridine, and 4-N,N-dimethylamino pyridine （DMAP）, on the oxidation of toluene catalyzed by cobalt acetate and benzyl bromide was investigated. DMAP showed improvement for the activity. The promoting effect was discussed.

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非金属催化环己烷选择氧化及其微反应技术研究
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生物质基多羟基化合物的催化选择氧化研究
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期刊信息
  • 《催化学报》
  • 北大核心期刊（2011版）
  • 主管单位:中国科学院
  • 主办单位:中国化学会 中国科学院大连化学物理研究所
  • 主编：李灿 张涛
  • 地址：大连市沙河口区中山路457号
  • 邮编：116023
  • 邮箱：chxb@dicp.ac.cn
  • 电话：0411-84379240
  • 国际标准刊号：ISSN：0253-9837
  • 国内统一刊号：ISSN：21-1195/O6
  • 邮发代号:8-93
  • 获奖情况:
  • 第三届国家期刊奖提名奖,中国科协精品科技期刊示范项目
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘（网络版）,荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,美国科学引文索引（扩展库）,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊（2004版）,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）,英国英国皇家化学学会文摘,中国北大核心期刊（2000版）
  • 被引量:19199