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Conductive resilient graphene aerogel via magnesio- thermic reduction of graphene oxide assemblies
  • 时间:0
  • 分类:O646.21[理学—物理化学;理学—化学]
  • 作者机构:[1]同济大学上海特殊人工微结构材料与技术重点实验室,上海200092
  • 相关基金:国家自然科学基金项目(No.512722179,51472182);上海市科委科研计划项目(13JC1408700).
中文摘要:

最近,包覆氧化物进行表面修饰的方法已成功应用于改善锂离子电池阴极材料的容量稳定性。本文中,我们通过V2O5溶胶结合提拉法制备了V2O5多孔薄膜,并利用原子层沉积法对其包覆Al2O3原子层。V2O5多孔薄膜的电化学性质受包覆层厚度的影响,我们研究了不同薄膜厚度下的修饰效果。结果显示,原子层沉积法包覆不同厚度Al2O3原子层对锂离子电池的循环稳定性都有所改善,经10个ALD包覆循环的样品表现出最好的修饰效果。在此基础上,我们讨论探索了包覆Al2O3对容量及稳定性增强的机理。

英文摘要:

Surface modification by coating oxides has been applied to improve the cyclic stability of cathode materials for rechargeable lithium-ion batteries. In this article, we systematically compared the improvement that resulted from different layers of Al2O3 coatings via atomic layer deposition (ALD)on V2O5 thin films. The porous V2O5 thin films were prepared by dip-coating method with vanadium oxide so1. The results reveal that the Al2O3 coatings have a positive effect to the cyclic durability. The film deposited by 10 layers of Al2O3 exhibits the best cyclic performance. Moreover, we further discussed the mechanism of the stability and capacity enhancement aroused from Al2O3 depositions.

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