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Charge transport in organic semiconductors: From incoherent to coherent
  • ISSN号:1001-6538
  • 期刊名称:Chinese Science Bulletin
  • 时间:2013.8
  • 页码:2669-2676
  • 分类:TN304.12[电子电信—物理电子学] TQ655[化学工程—精细化工]
  • 作者机构:[1]Key Laboratory of Micro- and Nano-Photonic Structures (Ministry of Education) and State Key Laboratory of Surface Physics, Fudan University, Shanghai 200433, China
  • 相关基金:Project supported by the National Natural Science Foundation of China (Grant No. 11134002) and the National Science and Technology Major Project of the Ministry of Science and Technology of China (Grant No. 2012CB921401).
  • 相关项目:有机半导体中载流子输运特性的理论研究
中文摘要:

Non-monotonic, asymmetrical electric field dependence of photoluminescence(PL) intensity is observed in a monolayer sample of tris-(8-hydroxyquinoline) aluminum(AlQ) doped N,N’-bis(3-methylphenyl)-N,N’-bis(phenyl)-benzidine(TPD). A possible model is proposed: the charge separation from the dissociated photoexcited excitons causes energy band bending in the organic films and improves the hole injection from the electrode, which brings about the extra fluorescence.This mechanism is further verified by a series of experiments using a series of samples, variously featuring symmetrical electrodes, block layers, and hosts with lower hole mobilities.

英文摘要:

Non-monotonic, asymmetrical electric field dependence of photoluminescence (PL) intensity is observed in a mono- layer sample of tris-(8-hydroxyquinoline) aluminum (A1Q) doped N,N'-bis(3-methylphenyl)-N,N'-bis(phenyl)-benzidine (TPD). A possible model is proposed: the charge separation from the dissociated photoexcited excitons causes energy band bending in the organic films and improves the hole injection from the electrode, which brings about the extra fluorescence. This mechanism is further verified by a series of experiments using a series of samples, variously featuring symmetrical electrodes, block layers, and hosts with lower hole mobilities.

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